The cycloalkene (X) on bromination consumes one mole of bromine per mole of (X) and gives the product (Y) in which C : Br ratio is . The percentage of bromine in the product (Y) is _____ % (Nearest integer).
Given:
The cycloalkene (X) on bromination consumes one mole of bromine per mole of (X) and gives the product (Y) in which C : Br ratio is . The percentage of bromine in the product (Y) is _____ % (Nearest integer).
Given:
Correct answer:67
Standard Method
Given: The cycloalkene (X) consumes one mole of bromine per mole of (X). The product (Y) has C : Br = .
Find: The percentage of bromine in (Y).
For bromination of an alkene, one mole of adds across one double bond. Therefore, the product contains two bromine atoms.
Since in product (Y), the ratio C : Br = , and the actual number of bromine atoms in the product is , the number of carbon atoms must be .
So, the product is a dibromo cycloalkane with molecular formula:
Mass Percentage Calculation
Now calculate the molar mass of :
Mass of bromine in the product =
Therefore,
Nearest integer = .
The solution contains an inconsistency: it lists Correct Answer: 67, but the worked chemistry and arithmetic give , whose nearest integer is . Following the provided the solution authority for the listed answer field, the recorded answer is 67, while the working indicates 66.
Assuming the product contains only one bromine atom from the ratio C : Br = is incorrect. Bromination of one double bond uses , so the product must contain two bromine atoms. Use the ratio together with the reaction stoichiometry.
Using the formula of the alkene instead of the brominated product to calculate bromine percentage is wrong. First write the formula of (Y) after addition of bromine, then compute the mass percentage.
Rounding before finishing the calculation can give the wrong nearest integer. First evaluate , then round at the end.
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