JEE Chemistry

Electrophilic Substitution in Benzene: JEE Questions & Solutions

24 previous-year JEE Chemistry questions on Electrophilic Substitution in Benzene, each with a worked step-by-step solution.

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Previous-year questions

  1. 01View questionNVAMediumJEE 2026
  2. 02Consider the following sequence of reactions. The number of bromine atom(s) in the final product (P) will be:MCQMediumJEE 2026
  3. 03Given below are two statements: Statement I: Benzene is nitrated to give nitrobenzene, which on further treatment with CH₃COCl / AlCl₃ will…MCQEasyJEE 2026
  4. 04Consider the following compounds. Arrange these compounds in a n increasing order of reactivity with nitrating mixture. The correct order…MCQMediumJEE 2026
  5. 05Consider the following reaction of benzene. In compound (Q), the percentage of oxygen is %. (Nearest integer)NVAMediumJEE 2026
  6. 06Method used for separation of mixture of products (B and C) obtained in the following reaction is:MCQMediumJEE 2026
  7. 07Which of the following reaction is NOT correctly represented?MCQEasyJEE 2026
  8. 08Identify the correct statements: The presence of –NO₂ group in benzene ring A. activates the ring towards electrophilic substitutions. B.…MCQEasyJEE 2026
  9. 09Consider the following sequence of reactions to produce major product (A): Molar mass of product (A) is g mol⁻¹. (Given molar mass in g…NVAMediumJEE 2025
  10. 10Identify correct statement/s: (A) -OCH₃ and -NHCOCH₃ are activating groups. (B) -CN and -OH are meta directing groups. (C) -CN and -SO₃H…MCQMediumJEE 2025
  11. 11For the reaction: The correct order of set of reagents for the above conversion is:MCQEasyJEE 2025
  12. 12Given below are two statements: Statement (I): On nitration of m-xylene with HNO₃, H₂SO₄, followed by oxidation, 4-nitrobenzene-1,…MCQEasyJEE 2025
  13. 13In the following series of reactions identify the major products A and B respectively.MCQMediumJEE 2025
  14. 14The sequence from the following that would result in giving predominantly 3, 4, 5-Tribromoaniline is:MCQMediumJEE 2025
  15. 15The major product (A) formed in the following reaction sequence isMCQMediumJEE 2025
  16. 16Benzene is treated with oleum to produce compound (X) which when further heated with molten sodium hydroxide followed by acidification…MCQEasyJEE 2025
  17. 17Choose the correct set of reagents for the following conversion:MCQMediumJEE 2025
  18. 18Among the following, total number of meta-directing functional groups is (Integer based): – OCH₃, –NO₂, –CN, –CH₃–NHCOCH₃, – COR, –OH, –…NVAEasyJEE 2024
  19. 19The products A and B formed in the following reaction scheme are respectively: 1. Benzene + HNO₃ + H₂SO₄ → A 2. A + Sn/HCl → BMCQEasyJEE 2024
  20. 20Number of compounds from the following which cannot undergo Friedel-Crafts reactions is: Toluene, nitrobenzene, xylene, cumene, aniline,…NVAEasyJEE 2024
  21. 21In the above conversion of compound (X) to product (Y), the sequence of reagents to be used will be:MCQMediumJEE 2023
  22. 22The major product 'P' formed in the given reaction is:MCQMediumJEE 2023
  23. 23Arrange the following compounds in increasing order of rate of aromatic electrophilic substitution reaction:MCQEasyJEE 2023
  24. 24Decreasing order of reactivity towards electrophilic substitution for the following compounds is:MCQEasyJEE 2023

Frequently asked questions

Our bank has 24 previous-year JEE Chemistry questions tagged to Electrophilic Substitution in Benzene, drawn from JEE papers between 2023 and 2026, including 8 from 2026 alone. Each comes with a full step-by-step solution.

Electrophilic Substitution in Benzene is rated Advanced overall for JEE Chemistry. The PYQs on this page break down as 13 medium, 11 easy.

Of the 24 previous-year questions on Electrophilic Substitution in Benzene, 19 are multiple-choice (MCQ) and 5 are numerical-value (NVA) questions.

Based on recent paper analysis, Electrophilic Substitution in Benzene is worth about 2 marks in JEE Main. It sits in Hydrocarbons, a Class 11 Chemistry chapter.

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