MCQEasyJEE 2026Alcohols

JEE Chemistry 2026 Question with Solution

A hydroxy compound (X)(X) with molar mass 122gmol1122\,g mol^{-1} is acetylated with acetic anhydride, using a large excess of the reagent ensuring complete acetylation of all hydroxyl groups. The product obtained has a molar mass of 290gmol1290\,g mol^{-1}. The number of hydroxyl groups present in compound (X)(X) is _____.

  • A

    33

  • B

    55

  • C

    44

  • D

    22

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: A hydroxy compound (X)(X) has molar mass 122gmol1122\,g mol^{-1}. After complete acetylation, the product has molar mass 290gmol1290\,g mol^{-1}.

Find: The number of hydroxyl groups present in compound (X)(X).

Step 1: Each hydroxyl group (OH)(-OH) on acetylation increases the molar mass by

42g mol142\,\text{g mol}^{-1}

Step 2: Total increase in molar mass is

ΔM=290122=168g mol1\Delta M = 290 - 122 = 168\,\text{g mol}^{-1}

Step 3: Therefore, the number of hydroxyl groups is

n=16842=4n = \frac{168}{42} = 4

Conclude: The compound (X)(X) contains 44 hydroxyl groups. The correct option is C.

Common mistakes

  • Assuming the entire mass of acetic anhydride is added for each hydroxyl group is incorrect because acetylation replaces the hydrogen of OH-OH, so the net mass increase per hydroxyl group is 42g mol142\,\text{g mol}^{-1}. Use the net increase, not the reagent molar mass.

  • Using the original molar mass 122gmol1122\,g mol^{-1} directly to count hydroxyl groups is wrong because the number of hydroxyl groups depends on the increase in molar mass after acetylation. First calculate 290122290 - 122.

  • Choosing the option from the answer key without verifying the calculation can be risky. Always compute ΔM\Delta M and divide by 4242 to confirm the number of hydroxyl groups.

Practice more Alcohols questions

Get unlimited AI-adaptive practice, mastery tracking, and an AI tutor that explains every step — free to start.

Related questions