MCQEasyJEE 2025Pressure & Temperature Relation

JEE Physics 2025 Question with Solution

The kinetic energy of translation of the molecules in 50g50 \, \text{g} of CO2_2 gas at 17C17^\circ \text{C} is:

  • A

    4102.8J4102.8 \, \text{J}

  • B

    4205.5J4205.5 \, \text{J}

  • C

    3986.3J3986.3 \, \text{J}

  • D

    3582.7J3582.7 \, \text{J}

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: mass of CO2_2 gas = 50g50 \, \text{g}, temperature = 17C17^\circ \text{C}.

Find: total translational kinetic energy of the molecules.

For an ideal gas, the total translational kinetic energy is

E=32nRTE = \frac{3}{2}nRT

where nn is the number of moles.

First, calculate the number of moles:

n=5044=1.136moln = \frac{50}{44} = 1.136 \, \text{mol}

Convert temperature to Kelvin:

T=17+273=290KT = 17 + 273 = 290 \, \text{K}

Now substitute in the formula:

E=32×1.136×8.314×290E = \frac{3}{2} \times 1.136 \times 8.314 \times 290 E=4102.8JE = 4102.8 \, \text{J}

Therefore, the translational kinetic energy is 4102.8J4102.8 \, \text{J}. The correct option is A.

Using molecules and Boltzmann constant

Given: mass of CO2_2 gas = 50g50 \, \text{g}, temperature = 17C17^\circ \text{C}.

Find: total translational kinetic energy of all molecules.

The translational kinetic energy per molecule is

32kT\frac{3}{2}kT

and total translational kinetic energy is

E=(32kT)×NE = \left(\frac{3}{2}kT\right) \times N

The number of molecules is obtained from moles:

N=5044×6.023×1023N = \frac{50}{44} \times 6.023 \times 10^{23}

Using this relation gives a value close to 4102.8J4102.8 \, \text{J}.

The first approach in the source shows 4108.644J4108.644 \, \text{J}, but the detailed substitution with E=32nRTE = \frac{3}{2}nRT gives 4102.8J4102.8 \, \text{J}, which matches option A and is the defensible answer.

Common mistakes

  • Using the mass 50g50 \, \text{g} directly in E=32nRTE = \frac{3}{2}nRT is wrong because the formula requires number of moles nn, not mass. First convert using n=mMn = \frac{m}{M}.

  • Keeping temperature as 1717 instead of converting to 290K290 \, \text{K} is incorrect because kinetic theory formulas require absolute temperature in Kelvin. Always use T=17+273T = 17 + 273.

  • Using the molar mass of CO2_2 incorrectly causes the final value to shift. The correct molar mass is 44g mol144 \, \text{g mol}^{-1}, so n=5044n = \frac{50}{44}.

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