MCQEasyJEE 2023Pressure & Temperature Relation

JEE Physics 2023 Question with Solution

A flask contains Hydrogen and Argon in the ratio 2:12:1 by mass. The temperature of the mixture is 30C30^\circ C. The ratio of average kinetic energy per molecule of the two gases (Kargon/Khydrogen)(K_{argon}/K_{hydrogen}) is: (Given: Atomic weight of Ar = 39.939.9)

  • A

    39.92\dfrac{39.9}{2}

  • B

    11

  • C

    39.939.9

  • D

    22

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: Hydrogen and Argon are in the same flask at temperature 30C30^\circ C.

Find: The ratio KargonKhydrogen\frac{K_{argon}}{K_{hydrogen}}.

The average kinetic energy per molecule of an ideal gas is

K=32kTK = \frac{3}{2}kT

where kk is the Boltzmann constant and TT is the absolute temperature.

Since average kinetic energy per molecule depends only on temperature, it does not depend on the mass or nature of the gas.

Both gases are at the same temperature in the same flask, so

Kargon=32kT,Khydrogen=32kTK_{argon} = \frac{3}{2}kT, \qquad K_{hydrogen} = \frac{3}{2}kT

Therefore,

KargonKhydrogen=32kT32kT=1\frac{K_{argon}}{K_{hydrogen}} = \frac{\frac{3}{2}kT}{\frac{3}{2}kT} = 1

Therefore, the ratio of average kinetic energies is 11. The correct option is B.

Concept Shortcut

Given: Both gases are in the same flask at the same temperature.

Find: The ratio of average kinetic energy per molecule.

Shortcut idea: For any ideal gas, average kinetic energy per molecule depends only on temperature. Therefore, if two gases have the same temperature, their average kinetic energies per molecule are equal.

So directly,

KargonKhydrogen=1\frac{K_{argon}}{K_{hydrogen}} = 1

Hence, the correct option is B.

Common mistakes

  • Using the mass ratio 2:12:1 to compare average kinetic energies. This is wrong because average kinetic energy per molecule depends only on temperature, not on how much of each gas is present. Use K=32kTK = \frac{3}{2}kT instead.

  • Assuming heavier Argon molecules must have greater average kinetic energy. This is wrong because molecular mass affects speed distribution, not the average kinetic energy at a fixed temperature. At the same temperature, both gases have the same average kinetic energy per molecule.

  • Using atomic weight of Ar = 39.939.9 in the ratio calculation. This is unnecessary here because the required quantity is average kinetic energy per molecule, which is independent of molar mass. Focus on the common temperature of the gases.

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