MCQEasyJEE 2023Bohr's Model & Hydrogen Spectrum

JEE Physics 2023 Question with Solution

The energy of He+^+ ion in its first excited state is, (The ground state energy for the Hydrogen atom is 13.6eV-13.6 \, \text{eV}):

  • A

    13.6eV-13.6 \, \text{eV}

  • B

    54.4eV-54.4 \, \text{eV}

  • C

    27.2eV-27.2 \, \text{eV}

  • D

    3.4eV-3.4 \, \text{eV}

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: He+^+ ion, first excited state so n=2n = 2, and the ground state energy for hydrogen is 13.6eV-13.6 \, \text{eV}.

Find: The energy of He+^+ ion in its first excited state.

For hydrogen-like ions, the energy levels are given by

En=13.6Z2n2eVE_n = -\frac{13.6 Z^2}{n^2} \, \text{eV}

Here, for He+^+, Z=2Z = 2.

For the first excited state, n=2n = 2. Substituting these values,

E2=13.6(2)2(2)2E_2 = -\frac{13.6 \cdot (2)^2}{(2)^2}

So,

E2=13.6eVE_2 = -13.6 \, \text{eV}

Therefore, the energy of the He+^+ ion in its first excited state is 13.6eV-13.6 \, \text{eV}. The correct option is A.

Common mistakes

  • Using the hydrogen value directly without applying the Z2Z^2 factor is incorrect because He+^+ is a hydrogen-like ion with nuclear charge Z=2Z = 2. Always use En=13.6Z2n2eVE_n = -\frac{13.6 Z^2}{n^2} \, \text{eV}.

  • Taking the first excited state as n=1n = 1 is wrong because the ground state is n=1n = 1 and the first excited state is n=2n = 2. Identify the quantum number before substitution.

  • Forgetting that the energy remains negative is a conceptual error because bound states of hydrogen-like ions have negative energy. Keep the negative sign throughout the calculation.

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