MCQMediumJEE 2026Bohr's Model & Hydrogen Spectrum

JEE Physics 2026 Question with Solution

In hydrogen atom spectrum, (RR → Rydberg's constant)

A. the maximum wavelength of the radiation of Lyman series is 43R\frac{4}{3R}

B. the Balmer series lies in the visible region of the spectrum

C. the minimum wavelength of the radiation of Paschen series is 9R\frac{9}{R}

D. the minimum wavelength of Lyman series is 54R\frac{5}{4R}

Choose the correct answer from the options given below :

  • A

    A, B and C Only

  • B

    A, B and D Only

  • C

    A, B Only

  • D

    B, D Only

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: Statements about hydrogen atom spectrum and Rydberg's constant RR.

Find: Which statements among A, B, C, D are correct.

Use the Rydberg formula:

1λ=R(1n121n22)\frac{1}{\lambda} = R\left(\frac{1}{n_1^2} - \frac{1}{n_2^2}\right)

Maximum wavelength corresponds to the smallest energy gap, so for a given series take n2=n1+1n_2 = n_1 + 1. Minimum wavelength corresponds to the series limit, so take n2=n_2 = \infty.

For Statement A: Lyman series has n1=1n_1 = 1. For maximum wavelength, take n2=2n_2 = 2.

1λ=R(114)=3R4\frac{1}{\lambda} = R\left(1 - \frac{1}{4}\right) = \frac{3R}{4}

Hence,

λ=43R\lambda = \frac{4}{3R}

So A is correct.

For Statement B: Balmer series corresponds to n1=2n_1 = 2 and it lies in the visible region of the spectrum. So B is correct.

For Statement C: Paschen series has n1=3n_1 = 3. For minimum wavelength, take n2=n_2 = \infty.

1λ=R(190)=R9\frac{1}{\lambda} = R\left(\frac{1}{9} - 0\right) = \frac{R}{9}

Hence,

λ=9R\lambda = \frac{9}{R}

So C is correct.

For Statement D: Lyman series minimum wavelength occurs at n2=n_2 = \infty.

1λ=R(10)=R\frac{1}{\lambda} = R(1 - 0) = R

Hence,

λ=1R\lambda = \frac{1}{R}

This is not 54R\frac{5}{4R}, so D is incorrect.

Therefore, the correct statements are A, B and C only. The correct option is A.

Series Limit Trick

Given: Hydrogen spectral series statements.

Find: The correct combination.

A quick way is to remember two facts:

  1. Maximum wavelength in a series comes from the first line of that series.
  2. Minimum wavelength comes from the series limit, that is n2=n_2 = \infty.
  • Lyman first line: 121 \to 2 gives
λ=43R\lambda = \frac{4}{3R}

So A is correct.

  • Balmer series is known to lie in the visible region, so B is correct.

  • Paschen limit: n1=3,n2=n_1 = 3, n_2 = \infty gives

λ=9R\lambda = \frac{9}{R}

So C is correct.

  • Lyman limit gives
λ=1R\lambda = \frac{1}{R}

not 54R\frac{5}{4R}, so D is incorrect.

Therefore, the correct option is A.

Common mistakes

  • Assuming minimum wavelength corresponds to the first line of a series. This is wrong because the first line gives the smallest energy gap and hence the maximum wavelength. For minimum wavelength, use the series limit with n2=n_2 = \infty.

  • Using the wrong lower level for a spectral series. This is wrong because each series has a fixed n1n_1: Lyman n1=1n_1=1, Balmer n1=2n_1=2, Paschen n1=3n_1=3. Always identify the correct series before substituting into the Rydberg formula.

  • Accepting statement D by confusing Lyman minimum wavelength with another transition value. This is wrong because for Lyman minimum wavelength,

    λ=1R\lambda = \frac{1}{R}

    not 54R\frac{5}{4R}. Always calculate the limit explicitly instead of guessing from nearby fractions.

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