MCQEasyJEE 2023Valency & Oxidation States

JEE Chemistry 2023 Question with Solution

The correct order of metallic character is:

  • A

    K>Be>Ca\text{K} > \text{Be} > \text{Ca}

  • B

    Be>Ca>K\text{Be} > \text{Ca} > \text{K}

  • C

    K>Ca>Be\text{K} > \text{Ca} > \text{Be}

  • D

    Ca>K>Be\text{Ca} > \text{K} > \text{Be}

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: The order of metallic character among K\text{K}, Be\text{Be}, and Ca\text{Ca} is to be determined.

Find: The correct decreasing order of metallic character.

Metallic character increases as we move down a group and decreases as we move across a period.

  • In a group, metallic character increases because atomic size increases and the attraction between valence electrons and the nucleus becomes weaker.
  • In a period, metallic character decreases because effective nuclear charge increases and loss of electrons becomes more difficult.

Applying these trends:

  • K\text{K} is more metallic than Ca\text{Ca}.
  • Ca\text{Ca} is more metallic than Be\text{Be}.

Therefore, the correct order of metallic character is

K>Ca>Be\text{K} > \text{Ca} > \text{Be}

So, the correct option is C.

Common mistakes

  • Assuming metallic character only increases down a group and ignoring the trend across a period. This is wrong because both group and period trends must be compared here. Check both positions in the periodic table before ordering the elements.

  • Confusing atomic size with metallic character without considering effective nuclear charge. This is wrong because across a period the increasing nuclear charge reduces metallic character. Use the periodic trend of ease of electron loss instead.

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