MCQEasyJEE 2023Ionic Equilibria & pH

JEE Chemistry 2023 Question with Solution

When the hydrogen ion concentration [H+][H^+] changes by a factor of 10001000, the value of pH of the solution:

  • A

    increases by 10001000 units

  • B

    decreases by 33 units

  • C

    decreases by 22 units

  • D

    increases by 22 units

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: The hydrogen ion concentration [H+][H^+] changes by a factor of 10001000.

Find: The change in pH of the solution.

Using the relation shown in the solution:

ΔpH=log(Δ[H+])\Delta pH = -\log(\Delta[H^+])

Since

Δ[H+]=1000=103\Delta[H^+] = 1000 = 10^3

therefore,

ΔpH=log(103)=3\Delta pH = -\log(10^3) = -3

So, the pH decreases by 33 units.

Discrepancy noted: The extracted solution text states "The Correct Option is A", but it also explicitly concludes "decreases by 3 units," which matches option B in the provided options. Therefore, the defensible correct option from the working is B.

Using pH definition

Given: pH=log[H+]\text{pH} = -\log[H^+] and [H+][H^+] changes by a factor of 10001000.

Find: How the pH changes.

If [H+][H^+] increases by a factor of 1000=1031000 = 10^3, then from the logarithmic definition, pH changes by the negative logarithm of that factor:

ΔpH=log(103)\Delta \text{pH} = -\log(10^3) ΔpH=3\Delta \text{pH} = -3

A negative change means the pH decreases by 33 units.

Therefore, the correct statement is decreases by 33 units, which corresponds to option B among the listed options.

Common mistakes

  • Using the factor 10001000 directly as the pH change. pH is a logarithmic scale, so a multiplicative change in [H+][H^+] becomes an additive change in pH through the logarithm. Use ΔpH=log(factor)\Delta \text{pH} = -\log(\text{factor}) instead.

  • Ignoring the negative sign in the pH relation. Since pH=log[H+]\text{pH} = -\log[H^+], an increase in [H+][H^+] causes pH to decrease. Always track the sign before choosing the option.

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