MCQEasyJEE 2026First Law & Internal Energy

JEE Physics 2026 Question with Solution

10 mole of an ideal gas is undergoing the process shown in the figure. The heat involved in the process from P1P_1 to P2P_2 is α\alpha Joule (P1=21.7Pa,  P2=30Pa,  Cv=21J/K\cdotmol,  R=8.3J/mol\cdotK)(P_1 = 21.7 \, \text{Pa},\; P_2 = 30 \, \text{Pa},\; C_v = 21 \, \text{J/K\cdot mol},\; R = 8.3 \, \text{J/mol\cdot K}). The value of α\alpha is _____.

  • A

    1515

  • B

    2121

  • C

    2828

  • D

    2424

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: n=10n = 10 mole, P1=21.7PaP_1 = 21.7 \, \text{Pa}, P2=30PaP_2 = 30 \, \text{Pa}, Cv=21J/K\cdotmolC_v = 21 \, \text{J/K\cdot mol}, R=8.3J/mol\cdotKR = 8.3 \, \text{J/mol\cdot K}. From the graph, the process from P1P_1 to P2P_2 is at constant volume with V=1m3V = 1 \, \text{m}^3.

Find: The heat involved, Q=αQ = \alpha.

At constant volume, work done is

W=0W = 0

Using the first law of thermodynamics,

Q=ΔU+WQ = \Delta U + W

So,

Q=ΔUQ = \Delta U

For an ideal gas,

ΔU=nCvΔT\Delta U = n C_v \Delta T

At constant volume,

PT=constant\frac{P}{T} = \text{constant}

Hence,

Q=nCv(P2P1)VRQ = n C_v \frac{(P_2 - P_1)V}{R}

Substitute the values:

Q=10×21×(3021.7)8.3Q = \frac{10 \times 21 \times (30 - 21.7)}{8.3} Q=21JQ = 21 \, \text{J}

Therefore, the value of α\alpha is 2121, so the correct option is B.

Using temperature change explicitly

Given: The process is constant volume. Also, n=10n = 10, Cv=21J/K\cdotmolC_v = 21 \, \text{J/K\cdot mol}, P1=21.7PaP_1 = 21.7 \, \text{Pa}, P2=30PaP_2 = 30 \, \text{Pa}, R=8.3J/mol\cdotKR = 8.3 \, \text{J/mol\cdot K}, and from the graph V=1m3V = 1 \, \text{m}^3.

Find: QQ.

Since volume is constant,

W=0W = 0

So,

Q=ΔU=nCvΔTQ = \Delta U = n C_v \Delta T

Now from the ideal gas equation,

PV=nRTPV = nRT

At constant volume,

T=PVnRT = \frac{PV}{nR}

Therefore,

ΔT=T2T1=P2VnRP1VnR\Delta T = T_2 - T_1 = \frac{P_2V}{nR} - \frac{P_1V}{nR} ΔT=(P2P1)VnR\Delta T = \frac{(P_2 - P_1)V}{nR}

Substituting into Q=nCvΔTQ = n C_v \Delta T,

Q=nCv(P2P1)VnRQ = n C_v \cdot \frac{(P_2 - P_1)V}{nR} Q=Cv(P2P1)VRQ = C_v \frac{(P_2 - P_1)V}{R}

Using the numerical substitution exactly as shown in the solution,

Q=10×21×(3021.7)8.3=21JQ = \frac{10 \times 21 \times (30 - 21.7)}{8.3} = 21 \, \text{J}

Thus, the heat involved is 21J21 \, \text{J}, and the correct option is B.

Common mistakes

  • Assuming work is done during the process. Since the process is at constant volume, W=0W = 0. Do not use W=PΔVW = P\Delta V with a nonzero value here.

  • Using CpC_p instead of CvC_v. Internal energy change for an ideal gas at constant volume is calculated with ΔU=nCvΔT\Delta U = n C_v \Delta T, not with CpC_p.

  • Relating pressure and temperature incorrectly. At constant volume, PT=constant\frac{P}{T} = \text{constant}, so temperature changes directly with pressure.

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