NVAEasyJEE 2026First Law & Internal Energy

JEE Physics 2026 Question with Solution

1010 mole of oxygen is heated at constant volume from 30C30 \, ^{\circ}\text{C} to 40C40 \, ^{\circ}\text{C}. The change in the internal energy of the gas is _____ cal.

(The molecular specific heat of oxygen at constant pressure, Cp=7cal/molCC_p = 7 \, \text{cal/mol} \, ^{\circ}\text{C} and R=2cal/molCR = 2 \, \text{cal/mol} \, ^{\circ}\text{C}.)

Answer

Correct answer:500

Step-by-step solution

Standard Method

Given: n=10n = 10 mol, temperature changes from 30C30 \, ^{\circ}\text{C} to 40C40 \, ^{\circ}\text{C}, Cp=7cal/molCC_p = 7 \, \text{cal/mol} \, ^{\circ}\text{C}, and R=2cal/molCR = 2 \, \text{cal/mol} \, ^{\circ}\text{C}.

Find: Change in internal energy ΔU\Delta U.

For an ideal gas,

ΔU=nCvΔT\Delta U = n C_v \Delta T

This relation is valid for any process. For constant volume, heat supplied equals the change in internal energy.

Using

CpCv=RC_p - C_v = R

we get

7Cv=27 - C_v = 2 Cv=5cal/molCC_v = 5 \, \text{cal/mol} \, ^{\circ}\text{C}

Now,

ΔT=4030=10C\Delta T = 40 - 30 = 10 \, ^{\circ}\text{C}

So,

ΔU=10×5×10=500cal\Delta U = 10 \times 5 \times 10 = 500 \, \text{cal}

Therefore, the change in internal energy is 500cal500 \, \text{cal}.

Using the heat capacity relation carefully

Given: The gas is heated at constant volume, with n=10n = 10 mol, Cp=7cal/molCC_p = 7 \, \text{cal/mol} \, ^{\circ}\text{C}, and R=2cal/molCR = 2 \, \text{cal/mol} \, ^{\circ}\text{C}.

Find: The value of ΔU\Delta U.

The required quantity is internal energy change, so the needed molar heat capacity is CvC_v, not CpC_p.

First use the relation

CpCv=RC_p - C_v = R

Substituting the values,

7Cv=27 - C_v = 2 Cv=5cal/molCC_v = 5 \, \text{cal/mol} \, ^{\circ}\text{C}

Now calculate the temperature rise:

ΔT=4030=10C\Delta T = 40 - 30 = 10 \, ^{\circ}\text{C}

For an ideal gas,

ΔU=nCvΔT\Delta U = n C_v \Delta T

Hence,

ΔU=10×5×10\Delta U = 10 \times 5 \times 10 ΔU=500cal\Delta U = 500 \, \text{cal}

Thus, the numerical answer is 500.

Common mistakes

  • Using CpC_p directly in ΔU=nCΔT\Delta U = n C \Delta T is incorrect because internal energy depends on CvC_v, not CpC_p. First find CvC_v from CpCv=RC_p - C_v = R.

  • Assuming the formula ΔU=nCvΔT\Delta U = n C_v \Delta T works only for constant-volume processes is wrong. For an ideal gas, internal energy change depends only on temperature change, regardless of the process.

  • Forgetting to compute the temperature difference and using the final temperature directly gives a wrong result. Use ΔT=4030=10C\Delta T = 40 - 30 = 10 \, ^{\circ}\text{C}.

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