mole of oxygen is heated at constant volume from to . The change in the internal energy of the gas is _____ cal.
(The molecular specific heat of oxygen at constant pressure, and .)
mole of oxygen is heated at constant volume from to . The change in the internal energy of the gas is _____ cal.
(The molecular specific heat of oxygen at constant pressure, and .)
Correct answer:500
Standard Method
Given: mol, temperature changes from to , , and .
Find: Change in internal energy .
For an ideal gas,
This relation is valid for any process. For constant volume, heat supplied equals the change in internal energy.
Using
we get
Now,
So,
Therefore, the change in internal energy is .
Using the heat capacity relation carefully
Given: The gas is heated at constant volume, with mol, , and .
Find: The value of .
The required quantity is internal energy change, so the needed molar heat capacity is , not .
First use the relation
Substituting the values,
Now calculate the temperature rise:
For an ideal gas,
Hence,
Thus, the numerical answer is 500.
Using directly in is incorrect because internal energy depends on , not . First find from .
Assuming the formula works only for constant-volume processes is wrong. For an ideal gas, internal energy change depends only on temperature change, regardless of the process.
Forgetting to compute the temperature difference and using the final temperature directly gives a wrong result. Use .
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