MCQMediumJEE Main 2026 · 21 January, Shift 1Gibbs Free Energy & Equilibrium Constant

Chemistry Question from JEE Main 2026 · 21 January, Shift 1

For the reaction, N2O42NO2N_{2}O_{4} \rightleftharpoons 2NO_{2} graph is plotted as shown below. Identify correct statements.

A. Standard free energy change for the reaction is 5.40kJ mol1-5.40 \, \text{kJ mol}^{-1}.

B. As ΔG\Delta G^\circ in graph is positive, N2O4N_{2}O_{4} will not dissociate into NO2NO_{2} at all.

C. Reverse reaction will go to completion.

D. When 11 mole of N2O4N_{2}O_{4} changes into equilibrium mixture, value of ΔG=0.84kJ mol1\Delta G = -0.84 \, \text{kJ mol}^{-1}.

E. When 22 mole of NO2NO_{2} changes into equilibrium mixture, ΔG\Delta G for equilibrium mixture is 6.24kJ mol1-6.24 \, \text{kJ mol}^{-1}.

Choose the correct answer from the options given below:

Graph of Gibbs free energy G in kJ mol inverse versus fraction of N2O4 dissociated, showing points B and E, equilibrium minimum, and marked values 5.40 and 0.84 under constant pressure and temperature.
  • A

    B and C only

  • B

    A and D only

  • C

    D and E only

  • D

    C and E only

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