MCQEasyJEE 2025Isomerism (Structural, Stereoisomerism)

JEE Chemistry 2025 Question with Solution

Consider the following molecule XX.

A fused bicyclic hydrocarbon structure labeled X, showing one five-membered ring fused with a six-membered ring and double bonds in three ring positions.

The structure of XX is:

Four structural options labeled 1 to 4, each showing a fused bicyclic ring system with different positions of bromine and hydrogen substituents.
  • A

    Option 11

  • B

    Option 22

  • C

    Option 33

  • D

    Option 44

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: A molecule XX is shown, and its correct structure must be identified from the four given options.

Find: Which option represents the structure of XX.

The solution identifies the ring system by visual comparison. It states that the given molecule appears as a fused bicyclic structure containing a five-membered ring fused with a six-membered ring.

By comparing the drawn framework of XX with the options, the matching structure is identified as the second option.

The extracted solution concludes that the structure corresponds to indene-like fused ring arrangement, and therefore the correct option is B.

Therefore, the correct option is B.

Visual Comparison of Ring Framework

Given: The molecule XX and four structural choices are provided.

Find: The option whose ring connectivity matches XX.

  1. First observe the fused ring framework in XX.
  2. The structure contains two fused rings with a characteristic arrangement of unsaturation.
  3. Compare this framework with each of the four options.
  4. The second option reproduces the same bicyclic connectivity and placement of double bonds.
  5. The other options differ because of bromine and hydrogen placement or mismatch in the ring arrangement.

Hence, on direct structural comparison, option 2 matches XX.

Therefore, the correct option is B.

Common mistakes

  • Focusing only on the presence of fused rings and ignoring the exact positions of the double bonds is incorrect. Several options have similar bicyclic skeletons. Match both the ring fusion and the unsaturation pattern.

  • Choosing a structure based only on substituents like Br\mathrm{Br} and H\mathrm{H} without first matching the parent carbon framework is wrong. First identify the core fused ring system, then check substituent placement.

  • Treating the answer key as numerical-value type is incorrect here. The question clearly provides four structural choices in the image, so it must be handled as an MCQ with options AA to DD.

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