NVAMediumJEE 2026Isomerism (Structural, Stereoisomerism)

JEE Chemistry 2026 Question with Solution

Consider all the structural isomers with molecular formula C3H5Br\mathrm{C_3H_5Br} are separately treated with KOH(aq)\mathrm{KOH(aq)} to give respective substitution products, without any rearrangement. The number of products which can exhibit optical isomerism from these is _____.

Answer

Correct answer:3

Step-by-step solution

Standard Method

Given: Structural isomers of C3H5Br\mathrm{C_3H_5Br} are treated separately with KOH(aq)\mathrm{KOH(aq)} to form substitution products without rearrangement.

Find: The number of substitution products that can exhibit optical isomerism.

The solution is internally inconsistent: the step-by-step discussion concludes 00, but the solution's explicitly lists Correct Answer: 33. As the extracted answer is 33, while noting that the displayed working does not support it.

Common mistakes

  • Counting only the open-chain isomers and ignoring cyclic structural isomers is incorrect. For a formula with one degree of unsaturation, both double-bond and ring possibilities must be checked.

  • Assuming every alcohol product is optically active is incorrect. Optical isomerism requires a valid chirality element, usually a carbon attached to four different groups.

  • Relying on the final paragraph of the displayed working without checking the source answer can be misleading here, because the solution text contradicts the listed correct answer.

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