MCQEasyJEE 2025Mean Free Path & Avogadro's Number

JEE Physics 2025 Question with Solution

The mean free path and the average speed of oxygen molecules at 300K300 \, \text{K} and 1atm1 \, \text{atm} are 3×107m3 \times 10^{-7} \, \text{m} and 600m/s600 \, \text{m/s}, respectively. Find the frequency of its collisions.

  • A

    2×1010/s2 \times 10^{10} / \mathrm{s}

  • B

    9×109/s9 \times 10^{9} / \mathrm{s}

  • C

    2×109/s2 \times 10^{9} / \mathrm{s}

  • D

    5×108/s5 \times 10^{8} / \mathrm{s}

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: Mean free path λ=3×107m\lambda = 3 \times 10^{-7} \, \text{m} and average speed cˉ=600m/s\bar{c} = 600 \, \text{m/s}.

Find: Frequency of collisions ff.

The frequency of molecular collisions is related to the mean free path and average speed by

f=cˉλf = \frac{\bar{c}}{\lambda}

Substituting the given values,

f=6003×107f = \frac{600}{3 \times 10^{-7}}

Therefore,

f=2×109s1f = 2 \times 10^{9} \, \text{s}^{-1}

Therefore, the frequency of collisions is 2×109s12 \times 10^{9} \, \text{s}^{-1}. The correct option is C.

Step-by-Step Computation

Given: λ=3×107m\lambda = 3 \times 10^{-7} \, \text{m} and cˉ=600m/s\bar{c} = 600 \, \text{m/s}.

Find: The collision frequency ff.

Concept Used: The frequency of molecular collisions is given by

f=cˉλf = \frac{\bar{c}}{\lambda}

where ff is in s1\text{s}^{-1}.

Step 1: Write the formula.

f=cˉλf = \frac{\bar{c}}{\lambda}

Step 2: Substitute the values.

f=6003×107f = \frac{600}{3 \times 10^{-7}}

Step 3: Simplify.

f=6003×107f = \frac{600}{3} \times 10^{7} f=200×107f = 200 \times 10^{7} f=2×109s1f = 2 \times 10^{9} \, \text{s}^{-1}

Therefore, the frequency of collisions is 2×109s12 \times 10^{9} \, \text{s}^{-1}.

Common mistakes

  • Using multiplication instead of division for collision frequency. This is wrong because the relation is f=cˉλf = \frac{\bar{c}}{\lambda}, not cˉ×λ\bar{c} \times \lambda. Always divide average speed by mean free path.

  • Handling the power of 10710^{-7} incorrectly. This is wrong because dividing by 10710^{-7} increases the value by a factor of 10710^{7}. Rewrite the denominator carefully before simplifying.

  • Ignoring units while substituting values. This is wrong because m/sm=s1\frac{\text{m/s}}{\text{m}} = \text{s}^{-1}, which confirms the quantity is a frequency. Check unit cancellation to verify the formula.

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