MCQEasyJEE 2023Mean Free Path & Avogadro's Number

JEE Physics 2023 Question with Solution

The number of air molecules per cm³ increased from 3×10193\times10^{19} to 12×101912\times10^{19}. The ratio of collision frequency of air molecules before and after the increase is:

  • A

    0.250.25

  • B

    0.750.75

  • C

    1.251.25

  • D

    0.500.50

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: Number density of air molecules changes from n1=3×1019n_1=3\times10^{19} to n2=12×1019n_2=12\times10^{19} per cm³.

Find: The ratio of collision frequency before and after the increase, i.e. Z1Z2\frac{Z_1}{Z_2}.

Collision frequency is given by

Z=nπd2vavgZ=n\pi d^2 v_{avg}

where nn is the number of molecules per unit volume.

Since dd and vavgv_{avg} remain constant,

Z1Z2=n1πd2vavgn2πd2vavg=n1n2\frac{Z_1}{Z_2}=\frac{n_1\pi d^2 v_{avg}}{n_2\pi d^2 v_{avg}}=\frac{n_1}{n_2}

Substituting the given values,

Z1Z2=3×101912×1019=312=14=0.25\frac{Z_1}{Z_2}=\frac{3\times10^{19}}{12\times10^{19}}=\frac{3}{12}=\frac{1}{4}=0.25

Therefore, the ratio of collision frequencies before and after the increase is 0.250.25. The correct option is A.

Using Proportionality of Collision Frequency

Given: Initial number density n1=3×1019n_1=3\times10^{19} and final number density n2=12×1019n_2=12\times10^{19}.

Find: Z1Z2\frac{Z_1}{Z_2}.

From the collision frequency formula,

Z=nπd2vavgZ=n\pi d^2 v_{avg}

This shows that collision frequency is directly proportional to number density:

ZnZ\propto n

Hence,

Z1Z2=n1n2\frac{Z_1}{Z_2}=\frac{n_1}{n_2}

Now substitute:

Z1Z2=3×101912×1019\frac{Z_1}{Z_2}=\frac{3\times10^{19}}{12\times10^{19}}

Cancel 101910^{19} from numerator and denominator:

Z1Z2=312=14=0.25\frac{Z_1}{Z_2}=\frac{3}{12}=\frac{1}{4}=0.25

Therefore, the required ratio is 0.250.25, so the correct option is A.

Common mistakes

  • Assuming collision frequency depends on the square of number density. That is incorrect here because the given formula is Z=nπd2vavgZ=n\pi d^2 v_{avg}, so ZZ is directly proportional to nn. Use a linear ratio, not a squared ratio.

  • Reversing the ratio as Z2Z1\frac{Z_2}{Z_1} instead of Z1Z2\frac{Z_1}{Z_2}. The question asks for before to after, so the correct setup is 3×101912×1019\frac{3\times10^{19}}{12\times10^{19}}.

  • Not cancelling the common factor 101910^{19}. This can make the calculation look complicated, but the power of ten is the same in numerator and denominator, so it cancels immediately.

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