MCQMediumJEE 2025Isomerism (Structural, Stereoisomerism)

JEE Chemistry 2025 Question with Solution

Identify the correct statements from the following

A.

Two ketone compounds are shown side by side and labelled as metamers, with different alkyl group distribution around the carbonyl group.

B.

Two nitrogen-containing compounds are shown side by side and labelled as functional isomers, one with CN and the other with NC attachment.

C.

Two alcohol structures are shown side by side and labelled as position isomers, with the OH group attached at different positions.

D.

Two amine-related organic compounds are shown side by side and labelled as homologous, one containing NH2 and the other containing NH within chain.

Choose the correct answer from the options given below

  • A

    C and D only

  • B

    B and C only

  • C

    A and B only

  • D

    A, B and C only

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: Four statements classify the shown pairs of organic compounds as metamers, functional isomers, position isomers, and homologous compounds.

Find: Which statements are correct.

From the provided solution analysis:

  1. Statement A is correct because the two ketone compounds have the same molecular formula and differ in the distribution of alkyl groups around the functional group, so they are metamers.
  2. Statement B is correct because the pair represents compounds with the same molecular formula but different functional groups, so they are functional isomers.
  3. Statement C is incorrect. The brief solution note states that the compounds in option C are homologues to each other, not position isomers.
  4. Statement D is incorrect because these are only organic molecules and are not isomers; they are not a homologous pair.
Annotated solution image marking statement A as metamer and statement B as functional group isomer with corresponding organic structures.

Therefore, the correct statements are A and B only.

The correct option is C.

Detailed Classification Check

Given: The task is to check whether each labelled pair has been identified correctly.

Find: The correct combination of statements.

The longer explanation on the page states:

  • A: correct as metamers.
  • B: correct as functional isomers.
  • C: the page text describes them as position isomers, but the shorter solution note says they are homologues. Since the final answer on the page concludes A and B only, statement C is treated as incorrect.
  • D: incorrect because the pair does not represent homologues in the intended sense.

Hence, the defensible conclusion from the solution is that only A and B are correct.

Therefore, the correct option is C.

Common mistakes

  • A common mistake is to mark C as correct by treating the pair as position isomers without checking the final conclusion of the solution. Here, the source solution ultimately accepts only A and B. Always reconcile individual observations with the final verified answer.

  • Students often confuse metamers with position isomers. Metamers must have the same functional group with different alkyl group distribution around that functional group, whereas position isomers keep the same carbon skeleton and shift the position of the functional group.

  • Another mistake is to treat any two similar-looking nitrogen compounds as homologues. Homologues must belong to the same functional family and differ regularly by a CH2\mathrm{CH_2} unit. If the functional connectivity changes, they may not be homologues.

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