MCQEasyJEE 2025Purification Methods (Crystallisation, Sublimation, Distillation)

JEE Chemistry 2025 Question with Solution

The purification method based on the following physical transformation is: SolidHeatVapourCoolSolid\text{Solid} \xrightarrow{\text{Heat}} \text{Vapour} \xrightarrow{\text{Cool}} \text{Solid}

  • A

    Distillation

  • B

    Sublimation

  • C

    Crystallization

  • D

    Extraction

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The physical transformation is

SolidHeatVapourCoolSolid\text{Solid} \xrightarrow{\text{Heat}} \text{Vapour} \xrightarrow{\text{Cool}} \text{Solid}

Find: The purification method represented by this transformation.

A substance that changes directly from solid to vapour on heating and directly back from vapour to solid on cooling undergoes sublimation.

This method is used to purify solids that pass directly between the solid and gaseous states without forming a liquid. Therefore, the purification method is Sublimation.

The correct option is B.

Stepwise Identification

Given: The transformation shown is

SolidHeatVapourCoolSolid\text{Solid} \xrightarrow{\text{Heat}} \text{Vapour} \xrightarrow{\text{Cool}} \text{Solid}

Find: Which purification method follows this sequence.

  1. On heating, the substance changes from solid directly to vapour.
  2. On cooling, the vapour changes directly back to solid.
  3. Since the liquid phase is skipped in both directions, the process is called sublimation.
  4. This purification method is used for substances such as iodine, camphor, naphthalene, and ammonium chloride.

Therefore, the correct answer is Sublimation, so the correct option is B.

Common mistakes

  • Confusing sublimation with distillation. Distillation involves liquid-to-vapour conversion and condensation, whereas here the change is directly from solid to vapour. Look for the absence of the liquid state.

  • Assuming any cooling-based purification is crystallization. Crystallization usually involves formation of crystals from a solution or melt, not direct vapour-to-solid conversion.

  • Ignoring the phase-change sequence shown in the transformation. The arrows explicitly indicate solid → vapour → solid, which is the defining feature of sublimation. Always identify the states first.

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