NVAEasyJEE Main 2025 · 23 January, Shift 2Internal Energy & Enthalpy

Chemistry Question from JEE Main 2025 · 23 January, Shift 2

The bond dissociation enthalpy of X2X_2 calculated from the given data is _____ kJ mol−1^{-1} (nearest integer).

Given:

M+X−(s)→M+(g)+X−(g)M^+X^-(s) \rightarrow M^+(g) + X^-(g), ΔHlattice∘=800 kJ mol−1\Delta H^\circ_{\text{lattice}} = 800 \, \text{kJ mol}^{-1}

M(s)→M(g)M(s) \rightarrow M(g), ΔHsub∘=100 kJ mol−1\Delta H^\circ_{\text{sub}} = 100 \, \text{kJ mol}^{-1}

M(g)→M+(g)+e−(g)M(g) \rightarrow M^+(g) + e^-(g), ΔHi∘=500 kJ mol−1\Delta H^\circ_{i} = 500 \, \text{kJ mol}^{-1}

X(g)+e−(g)→X−(g)X(g) + e^-(g) \rightarrow X^-(g), ΔHeg∘=−300 kJ mol−1\Delta H^\circ_{\text{eg}} = -300 \, \text{kJ mol}^{-1}

M(s)+12X2(g)→M+X−(s)M(s) + \frac{1}{2} X_2(g) \rightarrow M^+X^-(s), ΔHf∘=−400 kJ mol−1\Delta H^\circ_{f} = -400 \, \text{kJ mol}^{-1}

M+X−M^+X^- is a pure ionic compound and XX forms a diatomic molecule X2X_2 in the gaseous state.

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