MCQEasyJEE 2025Second Law & Heat Engines

JEE Physics 2025 Question with Solution

Water of mass mm gram is slowly heated to increase the temperature from T1T_1 to T2T_2. The change in entropy of the water, given specific heat of water is 1Jkg1K11 \, J \, kg^{-1} \, K^{-1}, is:

  • A

    zero

  • B

    m(T2T1)m (T_2 - T_1)

  • C

    mln(T1T2)m \ln \left( \frac{T_1}{T_2} \right)

  • D

    mln(T2T1)m \ln \left( \frac{T_2}{T_1} \right)

Answer

Correct answer:D

Step-by-step solution

Standard Method

Given: Water of mass mm is heated from T1T_1 to T2T_2. The specific heat is given as c=1Jkg1K1c = 1 \, J \, kg^{-1} \, K^{-1}.

Find: The change in entropy ΔS\Delta S.

For heating a substance, the entropy change is

ΔS=mcln(T2T1)\Delta S = m \cdot c \cdot \ln \left( \frac{T_2}{T_1} \right)

Substituting c=1c = 1,

ΔS=m1ln(T2T1)\Delta S = m \cdot 1 \cdot \ln \left( \frac{T_2}{T_1} \right)

So,

ΔS=mln(T2T1)\Delta S = m \ln \left( \frac{T_2}{T_1} \right)

Therefore, the change in entropy of the water is mln(T2T1)m \ln \left( \frac{T_2}{T_1} \right), so the correct option is D.

The other options are incorrect because entropy does not remain zero during heating, and the logarithmic temperature ratio must be ln(T2T1)\ln\left(\frac{T_2}{T_1}\right) for heating from T1T_1 to T2T_2.

Formula-Based Derivation

Given: Mass of water is mm, initial temperature is T1T_1, and final temperature is T2T_2.

Find: The entropy change during heating.

The change in entropy of a substance when its temperature changes is given by

ΔS=mcln(T2T1)\Delta S = m \cdot c \cdot \ln \left( \frac{T_2}{T_1} \right)

where mm is the mass, cc is the specific heat capacity, T1T_1 is the initial temperature, and T2T_2 is the final temperature.

Given c=1Jkg1K1c = 1 \, J \, kg^{-1} \, K^{-1}, the expression becomes

ΔS=mln(T2T1)\Delta S = m \cdot \ln \left( \frac{T_2}{T_1} \right)

Hence, the required entropy change is mln(T2T1)m \ln \left( \frac{T_2}{T_1} \right). This matches option D.

Common mistakes

  • Using T2T1T_2 - T_1 instead of the logarithmic ratio. This is wrong because entropy change for heating with constant specific heat depends on ln(T2T1)\ln\left(\frac{T_2}{T_1}\right), not directly on temperature difference. Use the entropy formula with the temperature ratio.

  • Reversing the ratio as ln(T1T2)\ln\left(\frac{T_1}{T_2}\right). This gives the wrong sign for heating. Since the water is heated from T1T_1 to T2T_2 with T2>T1T_2 > T_1, use ln(T2T1)\ln\left(\frac{T_2}{T_1}\right).

  • Assuming entropy change is zero. This is wrong because zero entropy change would require no thermal change or a reversible cycle returning to the same state. Here the temperature increases, so entropy must change.

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