Water of mass gram is slowly heated to increase the temperature from to . The change in entropy of the water, given specific heat of water is , is:
- A
zero
- B
- C
- D
Water of mass gram is slowly heated to increase the temperature from to . The change in entropy of the water, given specific heat of water is , is:
zero
Correct answer:D
Standard Method
Given: Water of mass is heated from to . The specific heat is given as .
Find: The change in entropy .
For heating a substance, the entropy change is
Substituting ,
So,
Therefore, the change in entropy of the water is , so the correct option is D.
The other options are incorrect because entropy does not remain zero during heating, and the logarithmic temperature ratio must be for heating from to .
Formula-Based Derivation
Given: Mass of water is , initial temperature is , and final temperature is .
Find: The entropy change during heating.
The change in entropy of a substance when its temperature changes is given by
where is the mass, is the specific heat capacity, is the initial temperature, and is the final temperature.
Given , the expression becomes
Hence, the required entropy change is . This matches option D.
Using instead of the logarithmic ratio. This is wrong because entropy change for heating with constant specific heat depends on , not directly on temperature difference. Use the entropy formula with the temperature ratio.
Reversing the ratio as . This gives the wrong sign for heating. Since the water is heated from to with , use .
Assuming entropy change is zero. This is wrong because zero entropy change would require no thermal change or a reversible cycle returning to the same state. Here the temperature increases, so entropy must change.
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