MCQEasyJEE 2023Second Law & Heat Engines

JEE Physics 2023 Question with Solution

An engine operating between the boiling and freezing points of water will have:

(1) efficiency more than 27%27\%.

(2) efficiency less than the efficiency a Carnot engine operating between the same two temperatures.

(3) efficiency equal to 27%27\%.

(4) efficiency less than 27%27\%.

  • A

    2,3 and 4 only2, 3 \text{ and } 4 \text{ only}

  • B

    2 and 3 only2 \text{ and } 3 \text{ only}

  • C

    2 and 4 only2 \text{ and } 4 \text{ only}

  • D

    1 and 2 only1 \text{ and } 2 \text{ only}

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The engine operates between the freezing point and boiling point of water.

Find: Which statements about efficiency are correct.

For a Carnot engine,

η=(1T2T1)×100\eta = \left(1 - \frac{T_2}{T_1}\right) \times 100

where T1T_1 and T2T_2 are the temperatures of the hot and cold reservoirs in Kelvin.

Here,

T1=100+273=373K,T2=0+273=273KT_1 = 100 + 273 = 373 \, \text{K}, \quad T_2 = 0 + 273 = 273 \, \text{K}

Substituting,

η=(1273373)×100=26.8%\eta = \left(1 - \frac{273}{373}\right) \times 100 = 26.8\%

So the Carnot efficiency between these temperatures is less than 27%27\%.

Now, any real engine operating between the same two temperatures has efficiency less than the Carnot engine. Therefore statement (2) is true.

Since even the maximum possible efficiency here is 26.8%26.8\%, statement (4) is true and statement (3) is false.

Thus the correct combination from the listed options should be 2 and 4 only2 \text{ and } 4 \text{ only}. However, the solution labels the correct option as B, while the options provided show 2 and 3 only2 \text{ and } 3 \text{ only} as option B. This is inconsistent with the working. Based on the solution working, the defensible answer is the option containing 2 and 4 only2 \text{ and } 4 \text{ only}.

Why Carnot sets the upper limit

Given: A heat engine works between 373K373 \, \text{K} and 273K273 \, \text{K}.

Find: Whether its efficiency can exceed, equal, or remain below 27%27\%.

A Carnot engine gives the maximum possible efficiency for any engine operating between the same two reservoirs. Therefore,

ηreal<ηCarnot\eta_{\text{real}} < \eta_{\text{Carnot}}

Now calculate the Carnot value:

ηCarnot=(1273373)×10026.8%\eta_{\text{Carnot}} = \left(1 - \frac{273}{373}\right) \times 100 \approx 26.8\%

Hence any actual engine must satisfy

ηreal<26.8%<27%\eta_{\text{real}} < 26.8\% < 27\%

So statement (2) is correct and statement (4) is correct. Statement (1) is impossible, and statement (3) is also false.

Therefore the correct option by working is C if the options are read as given here.

Common mistakes

  • Using temperatures in degree Celsius directly in the Carnot efficiency formula is incorrect because thermodynamic efficiency requires absolute temperature. Convert to K\text{K} first.

  • Assuming a real engine can have the same efficiency as a Carnot engine is wrong because Carnot efficiency is the maximum possible limit. A real engine must have lower efficiency.

  • Rounding 26.8%26.8\% to 27%27\% and then treating statement (3) as true is incorrect. The statement says equal to 27%27\%, not approximately equal.

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