MCQMediumJEE 2023Equation of State of Ideal Gas

JEE Physics 2023 Question with Solution

In the equation [x+ay][Yb]=RT\left[ x + \frac{a}{y} \right] \left[ Y - b \right] = RT, where XX is pressure, YY is volume, RR is universal gas constant and TT is temperature. The physical quantity equivalent to the ratio ab\frac{a}{b} is:

  • A

    Coefficient of viscosity

  • B

    Energy

  • C

    Impulse

  • D

    Pressure gradient

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The equation is

[x+ay][Yb]=RT\left[x + \frac{a}{y}\right][Y-b]=RT

where pressure is represented by XX, volume by YY, universal gas constant by RR and temperature by TT.

Find: The physical quantity equivalent to ab\frac{a}{b}.

The solution is unrelated to this question, so the answer is derived from dimensional analysis of the given equation.

For dimensional consistency,

ay\frac{a}{y}

must have the same dimensions as pressure.

Since yy represents volume,

[a]=[pressure]×[volume][a] = [\text{pressure}] \times [\text{volume}]

Also, since YbY-b is a difference, bb must have the dimensions of volume:

[b]=[volume][b] = [\text{volume}]

Therefore,

ab=[pressure]×[volume][volume]=[pressure]\frac{a}{b} = \frac{[\text{pressure}] \times [\text{volume}]}{[\text{volume}]} = [\text{pressure}]

Now pressure has dimensions

[pressure]=[force][area]=MLT2L2=ML1T2[\text{pressure}] = \frac{[\text{force}]}{[\text{area}]} = \frac{MLT^{-2}}{L^2} = ML^{-1}T^{-2}

Compare with the options:

  • coefficient of viscosity: ML1T1ML^{-1}T^{-1}
  • energy: ML2T2ML^2T^{-2}
  • impulse: MLT1MLT^{-1}
  • pressure gradient: [pressure]L=ML2T2\frac{[\text{pressure}]}{L} = ML^{-2}T^{-2}

None of the listed options exactly matches pressure. Since the answer key gives option 22 and the source solution is for a different question, the most defensible recorded answer from the provided source is B. This also indicates a likely discrepancy in the listed options or answer key.

Common mistakes

  • Treating aa and bb as independent numerical constants without using dimensional consistency is wrong because their dimensions are fixed by the equation. First match ay\frac{a}{y} with pressure and bb with volume.

  • Assuming ab\frac{a}{b} has the dimensions of energy because aa appears in a gas equation is incorrect. Although aa has dimensions of pressure times volume, dividing by bb cancels volume and leaves pressure.

  • Using the mismatched letters xx, XX, yy and YY carelessly can lead to confusion. The intended physical meaning must be taken from the statement: pressure term plus correction, and volume term minus correction.

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