NVAEasyJEE 2026Equation of State of Ideal Gas

JEE Physics 2026 Question with Solution

An insulated cylinder of volume 60cm360\,\text{cm}^3 is filled with a gas at 27C27^\circ\text{C} and 22 atmospheric pressure. The gas is then compressed making the final volume 20cm320\,\text{cm}^3 while allowing the temperature to rise to 77C77^\circ\text{C}. The final pressure is _____ atmospheric pressure.

Answer

Correct answer:7

Step-by-step solution

Standard Method

Given: V1=60cm3V_1 = 60\,\text{cm}^3, P1=2P_1 = 2 atmospheric pressure, T1=27CT_1 = 27^\circ\text{C}, V2=20cm3V_2 = 20\,\text{cm}^3, T2=77CT_2 = 77^\circ\text{C}.

Find: Final pressure P2P_2 in atmospheric pressure.

Step 1: Convert temperatures to Kelvin.

T1=27+273=300K,T2=77+273=350KT_1 = 27 + 273 = 300\,\text{K}, \quad T_2 = 77 + 273 = 350\,\text{K}

Step 2: Apply combined gas law.

P1V1T1=P2V2T2\frac{P_1V_1}{T_1} = \frac{P_2V_2}{T_2}

Step 3: Substitute given values.

2×60300=P2×20350\frac{2 \times 60}{300} = \frac{P_2 \times 20}{350}P2=2×60×350300×20=7\Rightarrow P_2 = \frac{2 \times 60 \times 350}{300 \times 20} = 7

Therefore, the final pressure is 77 atmospheric pressure.

Common mistakes

  • Using temperatures directly in degree Celsius is incorrect because the gas law requires absolute temperature. Convert 27C27^\circ\text{C} and 77C77^\circ\text{C} to 300K300\,\text{K} and 350K350\,\text{K} first.

  • Using Boyle's law alone is incorrect because the temperature also changes during compression. Use the combined gas law P1V1T1=P2V2T2\frac{P_1V_1}{T_1} = \frac{P_2V_2}{T_2} instead.

  • Reversing the final and initial volume terms gives the wrong pressure relation. Keep the corresponding states together: P1,V1,T1P_1, V_1, T_1 for the initial state and P2,V2,T2P_2, V_2, T_2 for the final state.

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