NVAEasyJEE 2023Hydrogen Bonding

JEE Chemistry 2023 Question with Solution

In an ice crystal, each water molecule is hydrogen bonded to:

Answer

Correct answer:4

Step-by-step solution

Standard Method

Given: In an ice crystal, each water molecule is hydrogen bonded to neighbouring water molecules.

Find: The number of hydrogen bonds associated with each water molecule.

In the ice crystal structure, each water molecule forms four hydrogen bonds with neighbouring water molecules.

A water molecule, H2O\mathrm{H_2O}, has two hydrogen atoms and one oxygen atom. It can donate two hydrogen bonds through its two hydrogen atoms and accept two hydrogen bonds through the two lone pairs present on oxygen.

Thus, total hydrogen bonds per water molecule in ice:

2+2=42 + 2 = 4

Therefore, each water molecule is hydrogen bonded to 44 neighbouring molecules.

Central water molecule in an ice crystal hydrogen bonded to four surrounding water molecules in a tetrahedral arrangement using dotted lines.

Hydrogen Bonding in Ice Crystal Structure

In an ice crystal, each water molecule forms four hydrogen bonds with its neighboring water molecules.

A water molecule, H2O\mathrm{H_2O}, has two hydrogen atoms and one oxygen atom. The oxygen atom is more electronegative than hydrogen, creating a polar molecule with a partial negative charge on oxygen and partial positive charges on the hydrogens.

Each water molecule can act as a hydrogen bond donor through its two hydrogen atoms. These slightly positive hydrogen atoms interact with the slightly negative oxygen atoms of neighboring water molecules, forming two hydrogen bonds.

Additionally, each water molecule can act as a hydrogen bond acceptor through its two lone pairs of electrons on oxygen. These lone pairs interact with the slightly positive hydrogen atoms of two other neighboring water molecules, forming two more hydrogen bonds.

Thus, each water molecule in ice participates in a total of four hydrogen bonds: two as a donor and two as an acceptor, creating a tetrahedral network structure.

Common mistakes

  • Counting only the two hydrogen atoms and concluding that one water molecule forms only 22 hydrogen bonds is incorrect. Water also accepts hydrogen bonds through the two lone pairs on oxygen. Count both donor and acceptor roles.

  • Confusing the number of covalent bonds in H2O\mathrm{H_2O} with the number of hydrogen bonds in ice leads to a wrong answer. The question asks about intermolecular hydrogen bonding, not the internal OH\mathrm{O-H} bonds.

  • Assuming liquid water and ice have the same instantaneous bonding picture can cause confusion. The question is specifically about the ice crystal structure, where the tetrahedral arrangement gives 44 hydrogen bonds per molecule.

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