MCQEasyJEE 2023Equation of State of Ideal Gas

JEE Physics 2023 Question with Solution

For three low density gases A, B, C pressure versus temperature graphs are plotted while keeping them at constant volume, as shown in the figure.

The temperature corresponding to the point 'K' is:

  • A

    273C-273^\circ \text{C}

  • B

    100C-100^\circ \text{C}

  • C

    373C-373^\circ \text{C}

  • D

    40C-40^\circ \text{C}

Answer

Correct answer:D

Step-by-step solution

Standard Method

Given: Pressure versus temperature graphs for low density gases AA, BB, CC are plotted at constant volume.

Find: The temperature corresponding to point KK.

For an isochoric process, the ideal gas law gives:

PT=nRV=constant\frac{P}{T} = \frac{nR}{V} = \text{constant}

So,

P=nRVTP = \frac{nR}{V}T

If Celsius temperature is tt, then absolute temperature is:

T=t+273T = t + 273

Hence,

P=nRV(t+273)P = \frac{nR}{V}(t+273)

At point KK, pressure is zero. Therefore,

0=nRV(t+273)0 = \frac{nR}{V}(t+273)

Since nRV0\frac{nR}{V} \neq 0, we get:

t+273=0t+273 = 0

Thus,

t=273Ct = -273^\circ \text{C}

Therefore, the temperature corresponding to point KK is 273C-273^\circ \text{C}. The solution working gives this value, although the solution incorrectly labels it as Option 4 / D.

Common mistakes

  • Using Celsius directly in PT\frac{P}{T} is incorrect because gas laws require absolute temperature in Kelvin. First convert using T=t+273T=t+273.

  • Reading the option label from the source solution without checking the value is incorrect. The working gives 273C-273^\circ \text{C}, which matches option A, not D.

  • Assuming P=0P=0 means the proportionality constant is zero is incorrect. At constant volume, nRV\frac{nR}{V} remains non-zero, so the zero must come from T=0KT=0\,\text{K}.

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