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JEE Chemistry 2023 Question with Solution

Match the reactions in List-I with the reagents in List-II:

  • A

    (A) – III, (B) – IV, (C) – II, (D) – I

  • B

    (A) – II, (B) – IV, (C) – I, (D) – III

  • C

    (A) – III, (B) – IV, (C) – I, (D) – II

  • D

    (A) – II, (B) – I, (C) – III, (D) – IV

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: A matching question between named reactions in List-I and reagents in List-II.

Find: The correct option that matches each reaction with its reagent.

From the extracted solution:

  • Hoffmann Degradation Reaction uses Br2Br_2 and NaOHNaOH to convert amides into amines. Therefore, reagent is (III).
  • Clemmensen Reduction reduces ketones or aldehydes to alkanes using ZnHgZn-Hg in HClHCl. Therefore, reagent is (IV).
  • Cannizzaro Reaction involves aldehydes without α\alpha-hydrogen in concentrated alkali. Therefore, reagent is (I).
  • Reimer-Tiemann Reaction introduces a CHO-CHO group into phenols using CHCl3CHCl_3 and NaOHNaOH. Therefore, reagent is (II).

So the final matching is:

(A)III,(B)IV,(C)I,(D)II(A) \to III, \quad (B) \to IV, \quad (C) \to I, \quad (D) \to II

This corresponds to Option C.

The solution states "The Correct Option is B", but its own working gives the mapping of Option C. Using the solution working, the defensible answer is C.

Common mistakes

  • Confusing Hoffmann degradation with other amine-forming reactions is a common mistake. Hoffmann degradation specifically uses Br2/NaOHBr_2/NaOH and converts an amide to an amine with one fewer carbon.

  • Mixing up Clemmensen reduction and other reduction methods leads to wrong matching. Clemmensen reduction uses ZnHg/HClZn-Hg/HCl in acidic medium, not basic conditions.

  • Assigning Cannizzaro reaction to aldehydes with α\alpha-hydrogen is incorrect. The reaction occurs for aldehydes without α\alpha-hydrogen in concentrated alkali.

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