In an Isothermal change, the change in pressure and volume of a gas can be represented for three different temperatures; as:
- A

- B

- C

- D

In an Isothermal change, the change in pressure and volume of a gas can be represented for three different temperatures; as:




Correct answer:D
Standard Method
Given: An isothermal change on a - graph for three temperatures satisfying .
Find: Which graph correctly represents the pressure-volume relation.
For an isothermal process, the relation is
So, the - curve is a rectangular hyperbola.
Also,
For the same amount of gas, a higher temperature means a larger value of . Therefore, the isotherm for higher temperature lies farther from the origin on the - graph.
Since , the outermost curve must correspond to , the middle curve to , and the innermost curve to .
Therefore, the correct graph is Option D.
Using the isobaric comparison shown in the solution
Given: Three isothermal curves and the condition .
Find: The correct ordering of curves on the - diagram.
The solution hint uses a horizontal dotted line, which represents an isobaric line, meaning pressure is the same for all three intersections.

At the same pressure, from the ideal gas law,
If is fixed, then
Hence, larger volume means higher temperature.
Along the dotted horizontal line, the curve intersecting at the largest volume corresponds to , then , and then . So the correct arrangement is the one where the hyperbolas move farther from the origin as temperature increases.
Therefore, the correct option is D.
Mistake: Choosing a graph with straight lines. Why it is wrong: an isothermal process satisfies , which gives a rectangular hyperbola, not a linear relation. What to do instead: first identify the functional form of the curve before comparing labels.
Mistake: Reversing the temperature order and placing higher temperature closer to the origin. Why it is wrong: from , larger temperature means larger , so the curve must lie farther from the origin. What to do instead: compare curves at the same pressure or same volume.
Mistake: Using the incorrect statement from part of the solution text that says . Why it is wrong: the question clearly states . What to do instead: follow the temperature order given in the question and then place the outermost isotherm at the highest temperature.
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