Given: Four statements about carbon are given, and we must identify the incorrect one.
Find: Which option contains the incorrect statement.
Check each statement one by one:
-
Option A: Carbon can show negative oxidation state −4 in CH4 and positive oxidation states such as +2 in CO and +4 in CO2. So this statement is correct.
-
Option B: Among the dioxides of group 14 elements, CO2 is the most acidic oxide. So this statement is correct.
-
Option C: 13C is a stable isotope, not a radioactive one. The radioactive isotope of carbon is 14C. Therefore, this statement is incorrect.
-
Option D: Carbon has no vacant d-orbitals and cannot expand its octet, so its maximum covalency is four. Hence this statement is correct.
Therefore, the incorrect statement is option C.