MCQEasyJEE 2024Group 14 Elements

JEE Chemistry 2024 Question with Solution

Consider the oxides of group 14 elements SiO2SiO_2, GeO2GeO_2, SnO2SnO_2, PbO2PbO_2, COCO, and GeOGeO.

The amphoteric oxides are:

  • A

    GeOGeO, GeO2GeO_2

  • B

    SiO2SiO_2, GeO2GeO_2

  • C

    SnO2SnO_2, PbO2PbO_2

  • D

    SiO2SiO_2, COCO

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: The oxides are SiO2SiO_2, GeO2GeO_2, SnO2SnO_2, PbO2PbO_2, COCO, and GeOGeO.

Find: Which of these are amphoteric oxides.

Amphoteric oxides react with both acids and bases.

From the given analysis:

  1. COCO is a neutral oxide, so it is not amphoteric.
  2. SiO2SiO_2 is acidic, so it is not amphoteric.
  3. GeOGeO is basic, so it is not amphoteric.
  4. GeO2GeO_2 is amphoteric.
  5. SnO2SnO_2 is amphoteric.
  6. PbO2PbO_2 is amphoteric.

Among the given options, the pair listed as amphoteric is SnO2SnO_2 and PbO2PbO_2.

Therefore, the correct option is C.

Common mistakes

  • Mistake: Treating COCO as an amphoteric oxide. Why it is wrong: COCO is classified as a neutral oxide. What to do instead: Distinguish clearly between acidic, basic, neutral, and amphoteric oxides before matching the option.

  • Mistake: Marking SiO2SiO_2 as amphoteric. Why it is wrong: SiO2SiO_2 is predominantly an acidic oxide. What to do instead: Recall the trend that lighter group 14 dioxides are more acidic, while heavier ones show amphoteric character.

  • Mistake: Choosing GeO2GeO_2 because it is amphoteric and then selecting the pair containing it. Why it is wrong: The question asks for the correct pair from the given options, not all amphoteric oxides individually. What to do instead: Check which complete option contains only the correct amphoteric oxides.

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