NVAMediumJEE Main 2026 · 24 January, Shift 1Faraday's Laws of Electrolysis

Chemistry Question from JEE Main 2026 · 24 January, Shift 1

Electricity is passed through an acidic solution of Cu2+\mathrm{Cu}^{2+} till all the Cu2+\mathrm{Cu}^{2+} was exhausted, leading to the deposition of 300mg300 \, \text{mg} of Cu metal. However, a current of 600mA600 \, \text{mA} was continued to pass through the same solution for another 28minutes28 \, \text{minutes} by keeping the total volume of the solution fixed at 200mL200 \, \text{mL}. The total volume of oxygen evolved at STP during the entire process is _____ mL\text{mL}. (Nearest integer)

Given: Cu2++2eCu(s)\mathrm{Cu}^{2+} + 2e^- \rightarrow \mathrm{Cu}(s) O2+4H++4e2H2O\mathrm{O_2} + 4H^+ + 4e^- \rightarrow 2H_2O

Molar mass of Cu\mathrm{Cu} = 63.54g mol163.54 \, \text{g mol}^{-1}

Faraday constant = 96500C mol196500 \, \text{C mol}^{-1}

Molar volume at STP = 22.4L22.4 \, \text{L}

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