MCQMediumJEE Main 2025 · 7 April, Shift 2Faraday's Laws of Electrolysis

Chemistry Question from JEE Main 2025 · 7 April, Shift 2

Given below are two statements :

1M1 \, \text{M} aqueous solution of each of Cu(NO3)2Cu(NO_3)_2, AgNO3AgNO_3, Hg2(NO3)2Hg_2(NO_3)_2; Mg(NO3)2Mg(NO_3)_2 are electrolysed using inert electrodes, Given : EAg+/Ag0=0.80VE^0_{Ag^+/Ag} = 0.80 \, \text{V}, EHg22+/Hg0=0.79VE^0_{Hg_2^{2+}/Hg} = 0.79 \, \text{V}, ECu2+/Cu0=0.24VE^0_{Cu^{2+}/Cu} = 0.24 \, \text{V} and EMg2+/Mg0=2.37VE^0_{Mg^{2+}/Mg} = -2.37 \, \text{V}

Statement (I) : With increasing voltage, the sequence of deposition of metals on the cathode will be Ag, Hg and Cu

Statement (II) : Magnesium will not be deposited at cathode instead oxygen gas will be evolved at the cathode.

In the light of the above statements, choose the most appropriate answer from the options given below :

  • A

    Both statement I and statement II are incorrect

  • B

    Statement I is correct but statement II is incorrect

  • C

    Both statement I and statement II are correct

  • D

    Statement I is incorrect but statement II is correct

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