NVAMediumJEE Main 2025 · 8 April, Shift 2Enthalpies (Bond, Combustion, Formation…)

Chemistry Question from JEE Main 2025 · 8 April, Shift 2

Resonance in X2YX_2Y can be represented as

Two resonance structures of X2Y are shown with charge separation, one with X=X=Y and the other with X≡X−Y, including lone pairs and formal charges on atoms.

The enthalpy of formation of X2YX_2Y (XX(g)+12Y=Y(g)X2Y(g))\left( X \equiv X(g) + \tfrac{1}{2} Y = Y(g) \rightarrow X_2Y(g) \right) is 80kJ mol180 \, \text{kJ mol}^{-1}. The magnitude of resonance energy of X2YX_2Y is _____ kJ mol1\text{kJ mol}^{-1} (nearest integer value).

Given: Bond energies of XXX \equiv X, X=XX = X, Y=YY = Y and X=YX = Y are 940940, 410410, 500500 and 602kJ mol1602 \, \text{kJ mol}^{-1} respectively.

Valency of XX: 33, of YY: 22.

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