NVAEasyJEE 2025First Law & Internal Energy

JEE Physics 2025 Question with Solution

An ideal gas has undergone through the cyclic process as shown in the figure. Work done by the gas in the entire cycle is _____ ×101\times 10^{-1} J. (Take π=3.14\pi = 3.14)

PV diagram showing a circular cyclic process centered near $$P = 400 \, \text{kPa}$$ and $$V = 250 \, \text{cm}^3$$, spanning pressure from $$300$$ to $$500 \, \text{kPa}$$ and volume from $$150$$ to $$350 \, \text{cm}^3$$.

Answer

Correct answer:31.4

Step-by-step solution

Standard Method

Given: The graph is a circle in the PVPV diagram for a cyclic process.

Find: Work done by the gas in the entire cycle.

For a cyclic process, the work done by the gas is equal to the area enclosed by the cycle.

From the graph:

  • Radius in pressure is RP=5003002=100kPaR_P = \frac{500 - 300}{2} = 100 \, \text{kPa}
  • Radius in volume is RV=3501502=100cm3R_V = \frac{350 - 150}{2} = 100 \, \text{cm}^3

Using the area of the circular loop,

Area=πR2=3.14×1002=3.14×104\text{Area} = \pi R^2 = 3.14 \times 100^2 = 3.14 \times 10^4

with units kPacm3\text{kPa} \cdot \text{cm}^3.

Now convert units:

1kPacm3=102J1 \, \text{kPa} \cdot \text{cm}^3 = 10^{-2} \, \text{J}

So,

W=3.14×104×102=314JW = 3.14 \times 10^4 \times 10^{-2} = 314 \, \text{J}

Hence, in the asked form,

W=31.4×101 JW = 31.4 \times 10^{-1} \text{ J}

Therefore, the required numerical value is 31.431.4.

Using ellipse area form

Given: The diameters of the circular path on the axes are read directly from the graph.

Find: The work done enclosed by the loop.

The enclosed area can also be written as

W=π4d1d2W = \frac{\pi}{4} d_1 d_2

where

d1=(500300)×103Pad_1 = (500 - 300) \times 10^3 \, \text{Pa}

and

d2=(350150)×106m3d_2 = (350 - 150) \times 10^{-6} \, \text{m}^3

Substituting,

W=π4(500300)×103×(350150)×106W = \frac{\pi}{4} (500 - 300) \times 10^3 \times (350 - 150) \times 10^{-6} W=3.144×200×103×200×106W = \frac{3.14}{4} \times 200 \times 10^3 \times 200 \times 10^{-6} W=31.4JW = 31.4 \, \text{J}

Thus the work done is 31.4J31.4 \, \text{J}.

Since the question asks for the value in the form _____ ×101\times 10^{-1} J, the required entry is 31.431.4.

Common mistakes

  • Treating the work done in a cyclic process as zero. This is wrong because over a complete cycle the change in internal energy may be zero, but the work done equals the area enclosed on the PVPV diagram. Always compute the enclosed area.

  • Using the full diameter as the radius. This is wrong because the pressure span is from 300300 to 500kPa500 \, \text{kPa} and the volume span is from 150150 to 350cm3350 \, \text{cm}^3, so the radius is half of each span, not the full difference.

  • Missing the unit conversion from kPacm3\text{kPa} \cdot \text{cm}^3 to joule. This gives an answer larger by a factor of 100100. Use 1kPacm3=102J1 \, \text{kPa} \cdot \text{cm}^3 = 10^{-2} \, \text{J}.

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