MCQMediumJEE 2025Isothermal & Adiabatic Processes

JEE Physics 2025 Question with Solution

A poly-atomic molecule (C3RC_3R, Cv=4RC_v = 4R, where RR is gas constant) goes from phase space point A (PA=104Pa,VA=4×103m3P_A = 10^4 \, Pa, V_A = 4 \times 10^{-3} \, m^3) to point B (PB=5×104Pa,VB=6×107m3P_B = 5 \times 10^4 \, Pa, V_B = 6 \times 10^{-7} \, m^3) to point C (PC=104Pa,VC=8×103m3P_C = 10^4 \, Pa, V_C = 8 \times 10^{-3} \, m^3). A to B is an adiabatic path and B to C is an isothermal path. The net heat absorbed per unit mole by the system is:

Pressure-volume graph showing points A, B, and C with dashed verticals at V_A, V_B, and V_C, an adiabatic path from A to B, and an isothermal path from B to C labeled 500 K and 450 K.
  • A

    500R(ln3+ln4)500R(\ln 3 + \ln 4)

  • B

    450R(ln3)450R(\ln 3)

  • C

    500R(ln2)500R(\ln 2)

  • D

    400Rln2400R \ln 2

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The process A to B is adiabatic and B to C is isothermal. We need the net heat absorbed per mole.

Find: Net heat absorbed by the system per mole.

For the total process,

ΔQ=ΔQadiabatic+ΔQisothermal\Delta Q = \Delta Q_{\text{adiabatic}} + \Delta Q_{\text{isothermal}}

For the adiabatic path A to B,

ΔQadiabatic=0\Delta Q_{\text{adiabatic}} = 0

For the isothermal path B to C, heat absorbed equals the work done:

ΔQisothermal=Wisothermal=nRTln(VCVB)\Delta Q_{\text{isothermal}} = W_{\text{isothermal}} = nRT \ln \left( \frac{V_C}{V_B} \right)

From the given solution working,

ΔQisothermal=450Rln(VCVB)=450R(ln3)\Delta Q_{\text{isothermal}} = 450R \ln \left( \frac{V_C}{V_B} \right) = 450R(\ln 3)

Hence,

ΔQ=0+450R(ln3)=450R(ln3)\Delta Q = 0 + 450R(\ln 3) = 450R(\ln 3)

Therefore, the net heat absorbed per mole is 450R(ln3)450R(\ln 3) and the correct option is B.

Using process-wise heat transfer

Given: One segment is adiabatic and the other is isothermal.

Find: Which segment contributes to heat absorption.

  1. In an adiabatic process, no heat is exchanged with the surroundings.
  2. Therefore, only the isothermal segment B to C contributes to the net heat absorbed.
  3. For an isothermal process of an ideal gas,
Q=nRTln(VfVi)Q = nRT \ln \left( \frac{V_f}{V_i} \right)
  1. Using the extracted solution result,
QBC=450R(ln3)Q_{BC} = 450R(\ln 3)

So the total heat absorbed over the complete path A \to B \to C is 450R(ln3)450R(\ln 3). Hence, the correct option is B.

Common mistakes

  • Assuming the adiabatic path also contributes heat transfer. This is wrong because by definition an adiabatic process has Q=0Q = 0. Only the isothermal segment contributes to the net heat absorbed here.

  • Using the internal energy change formula for the isothermal segment. This is wrong for an ideal gas in an isothermal process because ΔU=0\Delta U = 0, so the heat absorbed equals the work done, not nCvΔTnC_v\Delta T.

  • Substituting the wrong volume ratio in the logarithm, such as ln(VBVC)\ln\left(\frac{V_B}{V_C}\right) instead of ln(VCVB)\ln\left(\frac{V_C}{V_B}\right). This changes the sign of heat. For expansion from B to C, use final volume over initial volume.

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