MCQEasyJEE 2025Bohr's Model & Hydrogen Spectrum

JEE Physics 2025 Question with Solution

The frequency of revolution of the electron in Bohr’s orbit varies with nn, the principal quantum number as:

  • A

    1n3\frac{1}{n^3}

  • B

    1n4\frac{1}{n^4}

  • C

    1n\frac{1}{n}

  • D

    1n2\frac{1}{n^2}

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: The frequency of revolution of the electron in Bohr’s orbit is to be related with the principal quantum number nn.

Find: How the frequency varies with nn.

In Bohr’s model, the velocity of the electron in the nthn^{\text{th}} orbit varies as

vn1nv_n \propto \frac{1}{n}

and the radius of the nthn^{\text{th}} orbit varies as

rnn2r_n \propto n^2

The frequency of revolution is

f=vn2πrnf = \frac{v_n}{2\pi r_n}

Substituting the proportionalities,

f1/nn2=1n3f \propto \frac{1/n}{n^2} = \frac{1}{n^3}

Therefore, the frequency of revolution varies as 1n3\frac{1}{n^3}. The correct option is A.

Step-by-step Method

Given: In Bohr’s model of the hydrogen atom, the electron revolves in discrete circular orbits characterized by the principal quantum number nn.

Find: The dependence of frequency of revolution on nn.

Step 1: Understanding the concept. In Bohr’s model, the frequency of revolution depends on the electron speed and the orbit radius.

Step 2: Expression for velocity of the electron. According to Bohr’s theory, the velocity of the electron in the nthn^{\text{th}} orbit is given by

vn=e22ε0h1nv_n = \frac{e^2}{2\varepsilon_0 h} \cdot \frac{1}{n}

Thus,

vn1nv_n \propto \frac{1}{n}

Step 3: Expression for radius of the orbit. The radius of the nthn^{\text{th}} Bohr orbit is

rn=n2a0r_n = n^2 a_0

Hence,

rnn2r_n \propto n^2

Step 4: Frequency of revolution. The frequency of revolution ff is given by

f=vn2πrnf = \frac{v_n}{2\pi r_n}

Substituting the proportionalities of vnv_n and rnr_n,

f1/nn2=1n3f \propto \frac{1/n}{n^2} = \frac{1}{n^3}

Step 5: Final Answer. Therefore, the frequency of revolution of the electron in Bohr’s orbit varies as 1n3\frac{1}{n^3}. The correct option is A.

Common mistakes

  • Using only the velocity relation vn1nv_n \propto \frac{1}{n} and concluding that the frequency also varies as 1n\frac{1}{n}. This is wrong because frequency depends on both speed and orbit radius. Use f=vn2πrnf = \frac{v_n}{2\pi r_n}.

  • Forgetting that the Bohr radius varies as rnn2r_n \propto n^2. This leads to an incorrect power of nn in the denominator. Always combine the dependences of both vnv_n and rnr_n.

  • Confusing frequency of revolution with energy variation. The energy varies as 1n2\frac{1}{n^2}, but revolution frequency does not. Use the orbital motion formula instead of the energy formula.

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