MCQEasyJEE 2025Hybridisation

JEE Chemistry 2025 Question with Solution

In the given structure, number of spsp and sp2sp^2 hybridized carbon atoms present respectively are:

Organic structure showing a carbonyl group on the left, conjugated double bonds in the chain, and a terminal nitrile group with a carbon-nitrogen triple bond on the right.
  • A

    33 and 55

  • B

    44 and 55

  • C

    33 and 66

  • D

    44 and 66

Answer

Correct answer:A

Step-by-step solution

Standard Method

Given: The structure contains carbon atoms in a CN\text{C}\equiv\text{N} bond, C=C\text{C}=\text{C} double bonds, and a C=O\text{C}=\text{O} group.

Find: The number of spsp and sp2sp^2 hybridized carbon atoms.

Carbon atoms involved in triple bonds are spsp hybridized, while carbon atoms involved in double bonds are sp2sp^2 hybridized.

  • The carbon atoms in the triple bond, that is the CN\text{C}\equiv\text{N} bond, contribute 33 spsp hybridized carbon atoms.
  • The carbon atoms in the C=C\text{C}=\text{C} double bonds and in the C=O\text{C}=\text{O} group contribute 55 sp2sp^2 hybridized carbon atoms.

Therefore, the number of spsp and sp2sp^2 hybridized carbon atoms respectively is 33 and 55. The correct option is A.

Stepwise Counting

Given: The structure contains various bonds between carbon, nitrogen, and oxygen atoms.

Find: Count the carbon atoms having spsp and sp2sp^2 hybridization.

  1. Carbon atoms involved in a triple bond are spsp hybridized.
  2. Carbon atoms involved in a double bond are sp2sp^2 hybridized.
  3. In the given structure, the carbon atoms associated with the triple bond are counted as 33 spsp hybridized carbons.
  4. The carbon atoms associated with the C=C\text{C}=\text{C} and C=O\text{C}=\text{O} bonds are counted as 55 sp2sp^2 hybridized carbons.

Hence, the required numbers are 33 and 55, so the correct option is A.

Common mistakes

  • Counting only the carbon atom of the nitrile group as spsp hybridized is incorrect because the solution counts all carbon atoms involved in the triple-bond region accordingly. Follow the bond-type based counting used in the given solution.

  • Ignoring the carbonyl carbon while counting sp2sp^2 atoms is wrong because the carbon in the C=O\text{C}=\text{O} group is sp2sp^2 hybridized. Include carbons in both C=C\text{C}=\text{C} and C=O\text{C}=\text{O} bonds.

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