MCQEasyJEE 2025Equilibrium Basics

JEE Chemistry 2025 Question with Solution

For the reaction, H2(g)+I2(g)2HI(g)H_2(g) + I_2(g) \rightleftharpoons 2HI(g) Attainment of equilibrium is predicted correctly by:

Four concentration versus time graphs for H2, I2, and HI showing different ways concentrations change before reaching equilibrium.
  • A

    Graph 11

  • B

    Graph 22

  • C

    Graph 33

  • D

    Graph 44

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: The reaction is H2(g)+I2(g)2HI(g)H_2(g) + I_2(g) \rightleftharpoons 2HI(g).

Find: Which graph correctly shows attainment of equilibrium.

At equilibrium, the concentrations of reactants and products become constant, and the rates of the forward and reverse reactions become equal.

For this reaction, the concentrations of the reactants H2H_2 and I2I_2 decrease with time, while the concentration of the product HIHI increases with time. As equilibrium is attained, all three concentrations become constant.

Therefore, the correct graph is the one in which H2H_2 and I2I_2 decrease and level off, while HIHI increases and levels off.

The correct option is C.

Stepwise Interpretation

Given: The reaction is H2(g)+I2(g)2HI(g)H_2(g) + I_2(g) \rightleftharpoons 2HI(g).

Find: The graph that correctly represents attainment of equilibrium.

  1. Initially, the reactants H2H_2 and I2I_2 are consumed to form HIHI.
  2. Therefore, the concentrations of H2H_2 and I2I_2 should decrease with time.
  3. The concentration of HIHI should increase with time.
  4. When equilibrium is reached, the concentrations of all species stop changing and become constant.
  5. Hence, the correct graph must show decreasing curves for H2H_2 and I2I_2 and an increasing curve for HIHI, all eventually becoming horizontal.

Final Answer: Option (3), so the correct option is C.

Common mistakes

  • Assuming equilibrium means equal concentrations of H2H_2, I2I_2, and HIHI. This is incorrect because equilibrium requires constant concentrations, not necessarily equal concentrations. Look for curves that level off, not curves that meet at the same value.

  • Confusing equality of reaction rates with zero concentrations change from the start. The concentrations change until equilibrium is reached; only after that do they become constant. Choose the graph where the curves change first and then flatten.

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