NVAEasyJEE 2025Degrees of Freedom & Law of Equipartition

JEE Physics 2025 Question with Solution

The temperature of 11 mole of an ideal monoatomic gas is increased by 50C50^\circ \text{C} at constant pressure. The total heat added and change in internal energy are E1E_1 and E2E_2, respectively. If E1E2=x9\frac{E_1}{E_2} = \frac{x}{9}, then the value of xx is:

Answer

Correct answer:15

Step-by-step solution

Standard Method

Given: The process is isobaric and ΔT=50C\Delta T = 50^\circ \text{C}. The heat added is E1=Q=nCpΔTE_1 = Q = nC_p\Delta T and the change in internal energy is E2=ΔU=nCvΔTE_2 = \Delta U = nC_v\Delta T.

Find: The value of xx in E1E2=x9\frac{E_1}{E_2} = \frac{x}{9}.

For the ratio,

E1E2=nCpΔTnCvΔT=CpCv=γ\frac{E_1}{E_2} = \frac{nC_p\Delta T}{nC_v\Delta T} = \frac{C_p}{C_v} = \gamma

For a monoatomic ideal gas,

γ=1+2f\gamma = 1 + \frac{2}{f}

with f=3f = 3. Therefore,

γ=1+23=53\gamma = 1 + \frac{2}{3} = \frac{5}{3}

So,

E1E2=53\frac{E_1}{E_2} = \frac{5}{3}

Given that

E1E2=x9\frac{E_1}{E_2} = \frac{x}{9}

we get

53=x9\frac{5}{3} = \frac{x}{9}

Hence,

x=15x = 15

Therefore, the value of xx is 1515.

Using heat capacities directly

Given: Isobaric heating of 11 mole of a monoatomic ideal gas.

Find: The value of xx.

Use the standard values for a monoatomic gas:

Cp=52R,Cv=32RC_p = \frac{5}{2}R, \qquad C_v = \frac{3}{2}R

Then,

E1E2=nCpΔTnCvΔT=CpCv=52R32R=53\frac{E_1}{E_2} = \frac{nC_p\Delta T}{nC_v\Delta T} = \frac{C_p}{C_v} = \frac{\frac{5}{2}R}{\frac{3}{2}R} = \frac{5}{3}

Now compare with

x9=53\frac{x}{9} = \frac{5}{3}

So,

x=15x = 15

This works because in the ratio, both nn and ΔT\Delta T cancel out. Therefore, the value of xx is 1515.

Common mistakes

  • Using CvC_v for the heat added in an isobaric process is incorrect. At constant pressure, heat added is Q=nCpΔTQ = nC_p\Delta T. Use CpC_p for heat and CvC_v for change in internal energy.

  • Treating 50C50^\circ \text{C} differently from 50 K50 \text{ K} for temperature change leads to confusion. For a temperature interval, 50C=50 K50^\circ \text{C} = 50 \text{ K}, although here the ratio makes ΔT\Delta T cancel anyway.

  • Using the wrong value of γ\gamma is a common conceptual error. For a monoatomic ideal gas, degrees of freedom are f=3f=3, so γ=53\gamma = \frac{5}{3}, not 75\frac{7}{5} which applies to a diatomic gas under usual conditions.

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