MCQEasyJEE 2024Degrees of Freedom & Law of Equipartition

JEE Physics 2024 Question with Solution

The total kinetic energy of 1mole1 \, \text{mole} of oxygen at 27C27^\circ \text{C} is:

  • A

    6845.5J6845.5 \, \text{J}

  • B

    5942.0J5942.0 \, \text{J}

  • C

    6232.5J6232.5 \, \text{J}

  • D

    5670.5J5670.5 \, \text{J}

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: n=1n = 1 mole of oxygen and temperature T=27C=300KT = 27^\circ \text{C} = 300 \, \text{K}.

Find: The total kinetic energy of the gas.

For a diatomic gas like oxygen, the total kinetic energy is

E=52nRTE = \frac{5}{2} nRT

Using R=8.31J mol1K1R = 8.31 \, \text{J mol}^{-1} \text{K}^{-1}, substitute the values:

E=52×1×8.31×300E = \frac{5}{2} \times 1 \times 8.31 \times 300 E=6232.5JE = 6232.5 \, \text{J}

Therefore, the total kinetic energy is 6232.5J6232.5 \, \text{J}. The solution marks option A, but the calculated value matches option C in the given options. Hence, the correct option is C.

Using Degrees of Freedom

Given: Oxygen is a diatomic gas at 300K300 \, \text{K}.

Find: Total kinetic energy of 11 mole.

Use the relation

E=f2nRTE = \frac{f}{2} nRT

For a diatomic gas, f=5f = 5. So,

E=52×1×8.31×300=6232.5JE = \frac{5}{2} \times 1 \times 8.31 \times 300 = 6232.5 \, \text{J}

Therefore, the correct option is C.

Common mistakes

  • Using 32nRT\frac{3}{2}nRT instead of 52nRT\frac{5}{2}nRT is incorrect here because oxygen is a diatomic gas at ordinary temperature. Account for translational and rotational degrees of freedom.

  • Not converting 27C27^\circ \text{C} to Kelvin gives a wrong result. Always use absolute temperature in kinetic theory formulas, so take T=300KT = 300 \, \text{K}.

  • Trusting the option label written in the solution without checking the numerical value can be misleading. Match the computed value 6232.5J6232.5 \, \text{J} with the listed options before choosing the answer.

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