MCQEasyJEE 2025First Law & Internal Energy

JEE Physics 2025 Question with Solution

Using the given PP-VV diagram, the work done by an ideal gas along the path ABCDABCD is:

P-V diagram with points A, B, C, D marked on a rectangular path, pressure levels P0 and 2P0, and volume values V0, 2V0, and 3V0 with arrows showing path A to B to C to D.
  • A

    4P0V04 P_0 V_0

  • B

    3P0V03 P_0 V_0

  • C

    4P0V0-4 P_0 V_0

  • D

    3P0V0-3 P_0 V_0

Answer

Correct answer:D

Step-by-step solution

Standard Method

Given: The path ABCDABCD is shown on a PP-VV diagram.

Find: The work done by the ideal gas along the path ABCDABCD.

For a process on a PP-VV diagram, work done by the gas is

W=PdVW = \int P \, dV

That is, the work equals the signed area under the path. The sign depends on the direction of traversal.

The solution states that the path is traced counterclockwise, so the net work done by the gas is negative.

Using the segment-wise contribution given in the solution:

W=P0×2V0+2P0×(V0)+2P0×(V0)+P0×0W = P_0 \times 2V_0 + 2P_0 \times (-V_0) + 2P_0 \times (-V_0) + P_0 \times 0

So,

W=2P0V02P0V02P0V0W = 2P_0V_0 - 2P_0V_0 - 2P_0V_0

Hence,

W=3P0V0W = -3P_0V_0

Therefore, the correct option is D.

Area and Direction Interpretation

Given: A path ABCDABCD on the PP-VV plane with characteristic values P0P_0 and V0V_0.

Find: The net work done by the gas.

On a PP-VV diagram, only horizontal segments contribute directly to PdV\int P \, dV because vertical segments have dV=0dV = 0.

  • Along a rightward horizontal path, dV>0dV > 0, so work is positive.
  • Along a leftward horizontal path, dV<0dV < 0, so work is negative.
  • Along a vertical path, dV=0dV = 0, so work is zero.

From the provided working, the path is counterclockwise overall, which corresponds to net compression and therefore negative work done by the gas.

Adding the contributions exactly as given:

W=P0×2V0+2P0×(V0)+2P0×(V0)+P0×0=3P0V0W = P_0 \times 2V_0 + 2P_0 \times (-V_0) + 2P_0 \times (-V_0) + P_0 \times 0 = -3P_0V_0

Therefore, the work done by the gas is 3P0V0-3P_0V_0, so the correct option is D.

Common mistakes

  • Treating the work as always positive area is incorrect because the sign depends on the direction of traversal on the PP-VV diagram. For a counterclockwise path, the work done by the gas is negative.

  • Including work on vertical segments is incorrect because for those segments dV=0dV = 0. Use W=PdVW = \int P \, dV and note that constant-volume paths contribute zero work.

  • Ignoring whether the gas is expanding or compressing leads to sign errors. Rightward motion gives positive contribution, while leftward motion gives negative contribution.

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