MCQMediumJEE Main 2025 · 23 January, Shift 1Entropy & Spontaneity

Chemistry Question from JEE Main 2025 · 23 January, Shift 1

Ice at 5C-5^\circ C is heated to become vapor with temperature of 110C110^\circ C at atmospheric pressure. The entropy change associated with this process can be obtained from:

  • A

    268K383KCpdT+ΔHmelting273+ΔHboiling373\int_{268 \, K}^{383 \, K} C_p \, dT + \frac{\Delta H_{melting}}{273} + \frac{\Delta H_{boiling}}{373}

  • B

    268K273KCp,mTdT+ΔHm,fusionTf+ΔHm,vaporisationTb+273K373KCp,mTdT+373K383KCp,mTdT\int_{268 \, K}^{273 \, K} \frac{C_{p,m}}{T} \, dT + \frac{\Delta H_{m,\text{fusion}}}{T_f} + \frac{\Delta H_{m,\text{vaporisation}}}{T_b} + \int_{273 \, K}^{373 \, K} \frac{C_{p,m}}{T} \, dT + \int_{373 \, K}^{383 \, K} \frac{C_{p,m}}{T} \, dT

  • C

    268K373KCpdT+qrev\int_{268 \, K}^{373 \, K} C_p \, dT + q_{rev}

  • D

    268K273KCp,mdT+ΔHm,fusionTf+ΔHm,vaporisationTb+273K373KCp,mdT+373K383KCp,mdT\int_{268 \, K}^{273 \, K} C_{p,m} \, dT + \frac{\Delta H_{m,\text{fusion}}}{T_f} + \frac{\Delta H_{m,\text{vaporisation}}}{T_b} + \int_{273 \, K}^{373 \, K} C_{p,m} \, dT + \int_{373 \, K}^{383 \, K} C_{p,m} \, dT

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