NVAEasyJEE 2025Isothermal & Adiabatic Processes

JEE Physics 2025 Question with Solution

An ideal gas initially at 0C0^\circ \text{C} temperature, is compressed suddenly to one fourth of its volume. If the ratio of specific heat at constant pressure to that at constant volume is 32\frac{3}{2}, the change in temperature due to the thermodynamics process is _____ K\text{K}.

Answer

Correct answer:273

Step-by-step solution

Standard Method

Given: Initial temperature, T1=0C=273KT_1 = 0^\circ \text{C} = 273 \, \text{K}; final volume, V2=V14V_2 = \frac{V_1}{4}; ratio of specific heats, γ=CpCv=32\gamma = \frac{C_p}{C_v} = \frac{3}{2}.

Find: Change in temperature, ΔT\Delta T, during the sudden compression.

For a sudden adiabatic compression,

T2V2γ1=T1V1γ1T_2 V_2^{\gamma - 1} = T_1 V_1^{\gamma - 1}

Therefore,

T2T1=(V1V2)γ1\frac{T_2}{T_1} = \left(\frac{V_1}{V_2}\right)^{\gamma - 1}

Substituting the given values,

T2273=(V1V1/4)321\frac{T_2}{273} = \left(\frac{V_1}{V_1/4}\right)^{\frac{3}{2} - 1} T2273=412=2\frac{T_2}{273} = 4^{\frac{1}{2}} = 2

So,

T2=2×273=546KT_2 = 2 \times 273 = 546 \, \text{K}

Now the temperature change is,

ΔT=T2T1=546273=273K\Delta T = T_2 - T_1 = 546 - 273 = 273 \, \text{K}

Therefore, the temperature increases by 273K273 \, \text{K}.

Expanded Working

Given: T1=273KT_1 = 273 \, \text{K}, V2=V14V_2 = \frac{V_1}{4}, and γ=32\gamma = \frac{3}{2}.

Find: The value of ΔT\Delta T.

For an adiabatic process,

TVγ1=constantT V^{\gamma - 1} = \text{constant}

Hence,

T1V1γ1=T2V2γ1T_1 V_1^{\gamma - 1} = T_2 V_2^{\gamma - 1}

Rearranging,

T2=T1(V1V2)γ1T_2 = T_1 \left(\frac{V_1}{V_2}\right)^{\gamma - 1}

Using V2=V14V_2 = \frac{V_1}{4},

V1V2=V1V1/4=4\frac{V_1}{V_2} = \frac{V_1}{V_1/4} = 4

Also,

γ1=321=12\gamma - 1 = \frac{3}{2} - 1 = \frac{1}{2}

So,

T2=273×41/2=273×2=546KT_2 = 273 \times 4^{1/2} = 273 \times 2 = 546 \, \text{K}

Now,

ΔT=546273=273K\Delta T = 546 - 273 = 273 \, \text{K}

Therefore, the required change in temperature is 273K273 \, \text{K}.

Common mistakes

  • Using an isothermal relation such as PV=constantPV = \text{constant} is incorrect here because the compression is stated to be sudden, so it is treated as adiabatic. Use TVγ1=constantTV^{\gamma-1} = \text{constant} instead.

  • Taking the change in temperature as the final temperature is wrong. The question asks for the change, so after finding T2=546KT_2 = 546 \, \text{K}, compute ΔT=T2T1\Delta T = T_2 - T_1.

  • Forgetting to convert 0C0^\circ \text{C} to Kelvin leads to an incorrect calculation. Temperature relations in gas laws must be used in absolute scale, so take T1=273KT_1 = 273 \, \text{K}.

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