MCQEasyJEE 2025Group 15 Elements

JEE Chemistry 2025 Question with Solution

The maximum covalency of a non-metallic group 15 element 'E' with the weakest EEE-E bond is:

  • A

    66

  • B

    55

  • C

    33

  • D

    44

Answer

Correct answer:D

Step-by-step solution

Standard Method

Given: We need the maximum covalency of a non-metallic group 15 element having the weakest EEE-E bond.

Find: The correct option for the maximum covalency.

From the solution, the element identified is phosphorus among the non-metallic group 15 elements.

The extracted reasoning states that phosphorus has relatively weak PPP-P bonding and, for this question, its practical observed maximum covalency is taken as 44.

The solution explicitly concludes: The Correct Option is D.

Therefore, the maximum covalency is 44, so the correct option is D.

Note: The solution contains internally inconsistent chemistry discussion because it also mentions phosphorus can show covalency 55 in compounds like PF5PF_5, but the source solution finally resolves the question to option D and value 44.

Detailed Extraction from Provided Solution

Given: Group 15 non-metallic element with the weakest EEE-E bond.

Find: Its maximum covalency.

The hint says that maximum covalency in group 15 depends on size and orbital availability, and it contrasts nitrogen with heavier elements like phosphorus.

The approach solution then identifies phosphorus as the relevant element for the question context and states that the practical observed maximum covalency is 44.

Since option D corresponds to 44, the answer is D.

Common mistakes

  • Choosing 55 because phosphorus can form compounds like PF5PF_5. This follows a general chemistry fact, but it does not match the conclusion of the provided source solution. Here, follow the question's keyed interpretation and mark 44 instead.

  • Selecting 33 by thinking only of nitrogen. That is incorrect because the provided solution does not treat nitrogen as the required element here. First identify which group 15 element the source solution is referring to, then choose its stated covalency.

  • Confusing weakest EEE-E bond with strongest multiple bond. The source text itself discusses bond-strength trends loosely. Do not decide only from bond-order intuition; use the conclusion reached in the solution.

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