MCQEasyJEE 2025Electron Gain Enthalpy & Electronegativity

JEE Chemistry 2025 Question with Solution

Given below are two statements: Statement (I): An element in the extreme left of the periodic table forms acidic oxides. Statement (II): Acid is formed during the reaction between water and oxide of a reactive element present in the extreme right of the periodic table. In the light of the above statements, choose the correct answer from the options given below:

  • A

    Both Statement I and Statement II are false

  • B

    Statement I is true but Statement II is false

  • C

    Statement I is false but Statement II is true

  • D

    Both Statement I and Statement II are true

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: Two statements about the nature of oxides formed by elements at the extreme left and extreme right of the periodic table.

Find: Which statement is true or false and hence identify the correct option.

Elements on the extreme left of the periodic table are generally metals such as alkali metals and alkaline earth metals. These metals usually form basic oxides, not acidic oxides. Therefore, Statement (I) is false.

Elements on the extreme right of the periodic table are generally non-metals. Non-metal oxides are usually acidic oxides and can react with water to form acids. For example:

SO2+H2OH2SO3\text{SO}_2 + \text{H}_2\text{O} \rightarrow \text{H}_2\text{SO}_3

and

CO2+H2OH2CO3\text{CO}_2 + \text{H}_2\text{O} \rightarrow \text{H}_2\text{CO}_3

So, Statement (II) is true.

Therefore, the correct option is C.

Statement-wise Analysis

Given:

  1. Statement (I): An element in the extreme left of the periodic table forms acidic oxides.
  2. Statement (II): Acid is formed during the reaction between water and oxide of a reactive element present in the extreme right of the periodic table.

Find: The correct truth values of the two statements.

For Statement (I), the extreme left side of the periodic table contains highly electropositive metallic elements. Their oxides are generally basic in nature. Hence the claim that they form acidic oxides is incorrect.

For Statement (II), the extreme right side of the periodic table contains non-metals. Their oxides are generally acidic and react with water to give acids. Example:

SO2+H2OH2SO3\text{SO}_2 + \text{H}_2\text{O} \rightarrow \text{H}_2\text{SO}_3

Thus, this statement is correct.

Hence, Statement (I) is false but Statement (II) is true, so the correct option is C.

Common mistakes

  • Assuming that all oxides are acidic because they contain oxygen is incorrect. The nature of an oxide depends on whether the element is metallic or non-metallic. Metals on the left generally form basic oxides, while non-metals on the right generally form acidic oxides.

  • Confusing the periodic trend by reversing left and right sides of the periodic table leads to the wrong conclusion. The extreme left contains metallic elements, whereas the extreme right contains non-metals that commonly form acidic oxides.

  • Believing that reaction with water always produces a base is incorrect. Oxides of non-metals can react with water to form acids, so first identify whether the oxide is metallic or non-metallic before predicting the product.

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