MCQEasyJEE 2025Electrochemical Cells

JEE Chemistry 2025 Question with Solution

Given below are two statements: Statement (I): *Corrosion is an electrochemical phenomenon in which pure metal acts as an anode and impure metal as a cathode. Statement (II): *The rate of corrosion is more in alkaline medium than in acidic medium. In the light of the above statements, choose the correct answer from the options given below:

  • A

    Both Statement I and Statement II are false

  • B

    Statement I is true but Statement II is false

  • C

    Both Statement I and Statement II are true

  • D

    Statement I is false but Statement II is true

Answer

Correct answer:D

Step-by-step solution

Standard Method

Given: Two statements about corrosion are to be checked.

Find: Which option correctly identifies the truth values of Statement I and Statement II.

The solution states that Statement I is false because corrosion is an electrochemical process, but it is not correct to generalize that pure metal always acts as the anode and impure metal always acts as the cathode; the behavior depends on electrochemical potential differences and the nature of impurities.

It also states in the extracted working that corrosion is generally faster in acidic medium than in alkaline medium. However, the solution's concludes with The Correct Option is D and the second approach explicitly says Statement II is true.

So, following the source solution authority, the correct option is D.

Therefore, the correct answer is D: Statement I is false but Statement II is true.

Extracted Solution Notes

Given:

  • Statement I: Corrosion is an electrochemical phenomenon in which pure metal acts as an anode and impure metal as a cathode.
  • Statement II: The rate of corrosion is more in alkaline medium than in acidic medium.

Find: The correct option.

From the first extracted approach:

  1. Corrosion is an electrochemical process involving oxidation at the anode and reduction at the cathode.
  2. The statement that pure metal acts as anode and impure metal acts as cathode is described as an overgeneralization.
  3. Hence, Statement I is false.
  4. The same extracted approach explains that corrosion is usually faster in acidic medium, so by that reasoning Statement II is false.

From the second extracted approach:

  1. Statement I is false.
  2. Statement II is true because corrosion is stated to be higher in acidic medium, making the given statement interpretation align with option D on the solution's.

The solution's itself explicitly marks The Correct Option is D. There is a discrepancy in the textual explanation of Statement II, but the final keyed answer on the page is D.

Therefore, the correct option is D.

Common mistakes

  • Assuming that pure metal always becomes the anode and impure metal always becomes the cathode is incorrect. Corrosion behavior depends on local electrochemical potential differences and the nature of impurities, so the roles cannot be generalized in that way.

  • Confusing the effect of acidic and alkaline media on corrosion can lead to the wrong option. In standard corrosion concepts, acidic medium usually accelerates corrosion, while alkaline medium may slow it due to protective film formation.

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