MCQMediumJEE 2024First Law & Internal Energy

JEE Physics 2024 Question with Solution

A real gas within a closed chamber at 27C27\,\text{C} undergoes the cyclic process as shown in the figure. The gas obeys the PV3=RTPV^3 = RT equation for the path AA to BB. The net work done in the complete cycle is (assuming R=8J/mol\cdotKR = 8\,\text{J/mol\cdot K}):

  • A

    225J225\,\text{J}

  • B

    205J205\,\text{J}

  • C

    20J20\,\text{J}

  • D

    20J-20\,\text{J}

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The gas undergoes a cyclic process. For path AA to BB, PV3=RTPV^3 = RT and T=27C=300KT = 27^\circ\text{C} = 300\,\text{K}. Also, R=8J/mol\cdotKR = 8\,\text{J/mol\cdot K}.

Find: Net work done in the complete cycle.

For path ABAB:

WAB=PdVW_{AB} = \int P\,dV

Assuming temperature to be constant,

WAB=RTdVV3W_{AB} = \int \frac{RT\,dV}{V^3} =RT24V3dV= RT \int_{2}^{4} V^{-3}\,dV =8×300×(12[142122])= 8 \times 300 \times \left( -\frac{1}{2} \left[ \frac{1}{4^2} - \frac{1}{2^2} \right] \right) =225J= 225\,\text{J}

For path BCBC:

WBC=P42dV=10(24)=20JW_{BC} = P \int_{4}^{2} dV = 10(2 - 4) = -20\,\text{J}

For path CACA:

WCA=0W_{CA} = 0

Therefore,

Wcycle=WAB+WBC+WCA=22520+0=205JW_{\text{cycle}} = W_{AB} + W_{BC} + W_{CA} = 225 - 20 + 0 = 205\,\text{J}

Therefore, the net work done in the complete cycle is 205J205\,\text{J}. The correct option is B.

Area of cycle interpretation

Given: The process is cyclic and along AA to BB the gas obeys PV3=RTPV^3 = RT.

Find: Net work done over one complete cycle.

The work done in a cyclic process is the area enclosed by the loop on the PVP-V diagram. So we add the work contributions along each path.

Along ABAB, use

P=RTV3P = \frac{RT}{V^3}

and integrate with respect to volume from V=2V=2 to V=4V=4 to obtain 225J225\,\text{J}.

Along BCBC, pressure is constant at P=10P=10, so

WBC=PΔV=10(24)=20JW_{BC} = P\Delta V = 10(2-4) = -20\,\text{J}

Along CACA, volume is constant, hence no work is done:

WCA=0W_{CA} = 0

Thus, the enclosed net area, and hence the net work done in the cycle, is

205J205\,\text{J}

So the correct option is B.

Common mistakes

  • Using the cyclic-process idea incorrectly by setting net work to zero. In a cycle, the change in internal energy over one cycle may be zero, but the net work equals the area enclosed on the PVP-V diagram. Always compute the work along each path or the enclosed area.

  • Missing the sign of work on path BCBC. Since the volume decreases from 44 to 22, the work done by the gas is negative. Use W=PdVW = \int P\,dV carefully with the correct limits.

  • Treating the path CACA as doing nonzero work. A vertical line on a PVP-V diagram represents constant volume, so dV=0dV = 0 and therefore the work done is zero.

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