MCQEasyJEE 2024Batteries & Fuel Cells

JEE Chemistry 2024 Question with Solution

Match List-I (Cell) with List-II (Use/Property/Reaction):

List-I (Cell) | List-II (Use/Property/Reaction)

A. Leclanche cell | I. Converts energy of combustion into electrical energy B. Ni-Cd cell | II. Does not involve any ion in solution and is used in hearing aids C. Fuel cell | III. Rechargeable D. Mercury cell | IV. Reaction at anode: ZnZn2++2e\mathrm{Zn} \rightarrow \mathrm{Zn}^{2+} + 2e^-

  • A

    A-I, B-II, C-III, D-IV

  • B

    A-III, B-I, C-IV, D-II

  • C

    A-IV, B-III, C-I, D-II

  • D

    A-II, B-III, C-IV, D-I

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: We need to match the cells in List-I with their correct use/property/reaction in List-II.

Find: The correct matching set and hence the correct option.

  1. Leclanche cell is a primary cell in which zinc acts as the anode. The anode reaction is
ZnZn2++2e\mathrm{Zn} \rightarrow \mathrm{Zn}^{2+} + 2e^-

So, A \rightarrow IV.

  1. Ni-Cd cell is a rechargeable secondary cell. So, B \rightarrow III.

  2. Fuel cell converts the energy of combustion directly into electrical energy. So, C \rightarrow I.

  3. Mercury cell does not involve any ion in solution and is used in hearing aids. So, D \rightarrow II.

Therefore, the final match is A-IV, B-III, C-I, D-II.

The correct option is C.

Common mistakes

  • Confusing a primary cell with a secondary cell. Leclanche and mercury cells are primary cells, whereas Ni-Cd is rechargeable. Identify whether the cell can be recharged before matching its property.

  • Matching fuel cell with a generic electrode reaction instead of its defining use. A fuel cell is known for converting chemical energy of combustion into electrical energy, so it must be paired with statement I.

  • Assuming every cell involves ions in solution in the same way. The mercury cell is specifically known for not involving any ion in solution in the cell reaction; this is why it matches the hearing-aid statement.

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