MCQMediumJEE 2024First Law & Internal Energy

JEE Physics 2024 Question with Solution

A real gas within a closed chamber at 27C27^\circ \text{C} undergoes the cyclic process as shown in the figure. The gas obeys the PV3=RTPV^3 = RT equation for the path AA to BB. The net work done in the complete cycle is (assuming R=8J/mol\cdotKR = 8 \, \text{J/mol\cdot K}):

  • A

    225J225 \, \text{J}

  • B

    205J205 \, \text{J}

  • C

    20J20 \, \text{J}

  • D

    20J-20 \, \text{J}

Answer

Correct answer:B

Step-by-step solution

Standard Method

Given: The gas undergoes a cyclic process. Along path AA to BB, it obeys PV3=RTPV^3 = RT. Temperature is taken as T=300KT = 300 \, \text{K} since 27C=300K27^\circ \text{C} = 300 \, \text{K}, and R=8J/mol\cdotKR = 8 \, \text{J/mol\cdot K}.

Find: Net work done in the complete cycle.

Work done from AA to BB is

WAB=PdVW_{AB} = \int P \, dV

Assuming TT to be constant,

WAB=RTV3dVW_{AB} = \int \frac{RT}{V^3} \, dV

Using the given limits from V=2V=2 to V=4V=4,

WAB=RT24V3dVW_{AB} = RT \int_{2}^{4} V^{-3} \, dV WAB=8×300×(12[142122])W_{AB} = 8 \times 300 \times \left( -\frac{1}{2} \left[ \frac{1}{4^2} - \frac{1}{2^2} \right] \right) WAB=225JW_{AB} = 225 \, \text{J}

For path BB to CC,

WBC=P42dV=10(24)=20JW_{BC} = P \int_{4}^{2} dV = 10(2-4) = -20 \, \text{J}

For path CC to AA,

WCA=0W_{CA} = 0

Therefore, the net work done in the cycle is

Wcycle=WAB+WBC+WCA=22520+0=205JW_{\text{cycle}} = W_{AB} + W_{BC} + W_{CA} = 225 - 20 + 0 = 205 \, \text{J}

Therefore, the net work done in the complete cycle is 205J205 \, \text{J}. The correct option is B.

Area Under the Cycle

Given: The process is cyclic and the path AA to BB follows PV3=RTPV^3 = RT.

Find: The net work done over one complete cycle.

The work done in a cyclic process is the area enclosed by the loop on the PVP-V diagram. That means we add the work contributions along each segment.

From the provided working, the curved path ABA \to B contributes 225J225 \, \text{J}, the horizontal path BCB \to C contributes 20J-20 \, \text{J}, and the vertical path CAC \to A contributes 00 because dV=0dV=0 on that path.

Hence,

Wtotal=22520=205JW_{\text{total}} = 225 - 20 = 205 \, \text{J}

So, the net work done in the complete cycle is 205J205 \, \text{J}.

Common mistakes

  • Using 2727 directly instead of converting temperature to 300K300 \, \text{K} is incorrect because the gas equation uses absolute temperature. Always convert C^\circ \text{C} to K\text{K} before substitution.

  • Ignoring the sign of work along BCB \to C is wrong because the volume decreases from 44 to 22, so dV<0dV < 0 and the work is negative. Always track expansion and compression carefully.

  • Assuming nonzero work on CAC \to A is incorrect because that path is at constant volume, so dV=0dV = 0 and therefore W=PdV=0W = \int P \, dV = 0. For vertical lines on a PVP-V graph, work done is zero.

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