MCQEasyJEE 2024Bohr's Model & Hydrogen Spectrum

JEE Physics 2024 Question with Solution

A hydrogen atom in ground state is given an energy of 10.2eV10.2 \, \text{eV}. How many spectral lines will be emitted due to the transition of electrons?

  • A

    66

  • B

    33

  • C

    1010

  • D

    11

Answer

Correct answer:D

Step-by-step solution

Standard Method

Given: A hydrogen atom is initially in the ground state and is given energy 10.2eV10.2 \, \text{eV}.

Find: The number of spectral lines emitted due to the subsequent electronic transition.

For hydrogen atom, energy of the nthn^{\text{th}} orbit varies as

EZ2n2E \propto \frac{Z^2}{n^2}

The energy of the second orbit is

E2=13.64=3.4eVE_2 = \frac{-13.6}{4} = -3.4 \, \text{eV}

Hence, the energy difference for the transition 212 \to 1 is

ΔE21=10.2eV\Delta E_{2 \to 1} = 10.2 \, \text{eV}

So, the given energy excites the electron only from n=1n = 1 to n=2n = 2. After excitation, only one downward transition is possible:

n=2n=1n = 2 \to n = 1

Therefore, only one spectral line is emitted. The correct option is D.

Energy Level Interpretation

Given: The electron starts from the ground state n=1n = 1 and absorbs exactly 10.2eV10.2 \, \text{eV}.

Find: How many emission lines can appear when it returns to a lower level.

The energy gap between the ground state and the first excited state of hydrogen is approximately 10.2eV10.2 \, \text{eV}. Therefore, the electron is promoted from n=1n = 1 to n=2n = 2.

Once the electron reaches n=2n = 2, it has only one lower energy level available, namely n=1n = 1. Thus only one radiative transition can occur:

n=2n=1n = 2 \rightarrow n = 1

Therefore, the number of spectral lines emitted is 11, so the correct option is D.

Common mistakes

  • Assuming the electron can jump to many higher levels after absorbing 10.2eV10.2 \, \text{eV} is incorrect, because this energy matches only the gap between n=1n = 1 and n=2n = 2. Use the exact energy difference before counting transitions.

  • Using the formula for number of spectral lines, n(n1)2\frac{n(n-1)}{2}, with the wrong excited level is a common mistake. First identify the highest level reached; here it is only n=2n = 2, so the number of lines is 2(21)2=1\frac{2(2-1)}{2} = 1.

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