MCQEasyJEE 2024Bohr's Model & Hydrogen Spectrum

JEE Physics 2024 Question with Solution

An electron in a hydrogen atom has energy En=0.85eVE_n = -0.85 \, \text{eV} in an excited state. The maximum number of allowed transitions to lower energy levels is:

  • A

    44

  • B

    55

  • C

    66

  • D

    77

Answer

Correct answer:C

Step-by-step solution

Standard Method

Given: An electron in a hydrogen atom has energy En=0.85eVE_n = -0.85 \, \text{eV} in an excited state.

Find: The maximum number of allowed transitions to lower energy levels.

Use the Bohr model relation for hydrogen:

En=13.6n2eVE_n = -\frac{13.6}{n^2} \, \text{eV}

Substitute the given energy:

0.85=13.6n2-0.85 = -\frac{13.6}{n^2}

So,

n2=13.60.85=16n^2 = \frac{13.6}{0.85} = 16

Hence,

n=4n = 4

Now use the formula for the maximum number of allowed transitions from level nn:

Number of transitions=n(n1)2\text{Number of transitions} = \frac{n(n-1)}{2}

Substituting n=4n = 4,

Number of transitions=4(41)2=122=6\text{Number of transitions} = \frac{4(4-1)}{2} = \frac{12}{2} = 6

Therefore, the maximum number of allowed transitions is 66. The correct option is C.

Direct Formula Shortcut

Given: En=0.85eVE_n = -0.85 \, \text{eV}.

Find: The maximum number of transitions.

First identify the orbit using

En=13.6n2eVE_n = -\frac{13.6}{n^2} \, \text{eV}

Since

13.60.85=16\frac{13.6}{0.85} = 16

we get

n=4n = 4

For an electron in the 44th level, the maximum number of distinct downward transitions is directly

n(n1)2=4×32=6\frac{n(n-1)}{2} = \frac{4 \times 3}{2} = 6

This shortcut works because every pair of energy levels among the lower reachable levels gives one possible emission line. Therefore, the correct option is C.

Common mistakes

  • Using the wrong hydrogen energy formula is a common mistake. The correct relation is En=13.6n2eVE_n = -\frac{13.6}{n^2} \, \text{eV}, not a linear dependence on nn. Always solve for n2n^2 first.

  • Counting only direct transitions from n=4n=4 to n=3,2,1n=3,2,1 gives 33, which is incorrect. The question asks for the maximum number of allowed transitions among all lower levels, so use n(n1)2\frac{n(n-1)}{2}.

  • Ignoring the negative sign in energy can lead to confusion. The negative sign indicates a bound state; for finding nn, compare magnitudes consistently and solve the Bohr energy equation carefully.

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